Benzo-1,3,2-diazaphospholide and benzo-1,3,2-diazaphospholium: an isoelectronic aromatic anion-cation pair

Benzo-1,3,2-diazaphospholide and benzo-1,3,2-diazaphospholium: an isoelectronic aromatic anion-cation pair

Isoelectronic benzo-1,3,2-diazaphospholium cations and benzo-1,3,2-diazaphospholide anions were prepared from the same phosphazane precursor; both species display according to computational studies similar aromaticity as the neutral benzo-1,3,2-diazaphosphole but are chemically more stable due to th...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2009-01 (7), p.830-832
Hauptverfasser: Schmid, Dirk, Loscher, Sebastian, Gudat, Dietrich, Bubrin, Denis, Hartenbach, Ingo, Schleid, Thomas, Benko, Zoltán, Nyulászi, László
Format: Artikel
Sprache:eng
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Zusammenfassung:Isoelectronic benzo-1,3,2-diazaphospholium cations and benzo-1,3,2-diazaphospholide anions were prepared from the same phosphazane precursor; both species display according to computational studies similar aromaticity as the neutral benzo-1,3,2-diazaphosphole but are chemically more stable due to their ionic nature.
ISSN:1359-7345
1364-548X
DOI:10.1039/b817046k