Self-Assembly of Interpenetrating Coordination Nets Formed from Interpenetrating Cationic and Anionic Three-Dimensional Diamondoid Cluster Coordination Polymers

Self-Assembly of Interpenetrating Coordination Nets Formed from Interpenetrating Cationic and Anionic Three-Dimensional Diamondoid Cluster Coordination Polymers

Tetrathiometalates [WS4]2− are the nodal building blocks in a new kind of heterometallic interpenetrating three‐dimensional cluster coordination polymer (see picture) that has interesting nonlinear optical properties. The polymer exhibits optical self‐focusing behavior and reverse saturable absorpti...

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Veröffentlicht in:Angewandte Chemie International Edition 2004-11, Vol.43 (43), p.5776-5779
Hauptverfasser: Liang, Kai, Zheng, Hegen, Song, Yinglin, Lappert, Michael F., Li, Yizhi, Xin, Xinquan, Huang, Zixiang, Chen, Jiutong, Lu, Shaofang
Format: Artikel
Sprache:eng
Schlagworte:
clusters
coordination polymers
heterometallic complexes
nonlinear optics
organic-inorganic hybrid composites
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Zusammenfassung:Tetrathiometalates [WS4]2− are the nodal building blocks in a new kind of heterometallic interpenetrating three‐dimensional cluster coordination polymer (see picture) that has interesting nonlinear optical properties. The polymer exhibits optical self‐focusing behavior and reverse saturable absorption effects.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200460681