High-Quality 2D Metal−Organic Coordination Network Providing Giant Cavities within Mesoscale Domains

High-Quality 2D Metal−Organic Coordination Network Providing Giant Cavities within Mesoscale Domains

A surface-supported open metal−organic nanomesh featuring a 24 nm2 cavity size and extending to μm domains was fabricated by Co-directed assembly of para-hexaphenyl-dicarbonitrile linker molecules in two dimensions. The metallosupramolecular lattice is thermally robust and resides fully commensurate...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Journal of the American Chemical Society 2009-03, Vol.131 (11), p.3881-3883
Hauptverfasser: Kühne, Dirk, Klappenberger, Florian, Decker, Régis, Schlickum, Uta, Brune, Harald, Klyatskaya, Svetlana, Ruben, Mario, Barth, Johannes V
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:A surface-supported open metal−organic nanomesh featuring a 24 nm2 cavity size and extending to μm domains was fabricated by Co-directed assembly of para-hexaphenyl-dicarbonitrile linker molecules in two dimensions. The metallosupramolecular lattice is thermally robust and resides fully commensurate on the employed Ag(111) substrate as directly verified by high-resolution scanning tunneling microscopy observations.
ISSN:0002-7863
1520-5126
DOI:10.1021/ja809946z