A General and Efficient Copper Catalyst for the Double Carbonylation Reaction

A General and Efficient Copper Catalyst for the Double Carbonylation Reaction

The use of (NHC)CuI complex in combination with a N-heterocyclic carbene precursor as catalyst for the double carbonylation of aryl Iodides and secondary amines solves the problem of using the precious metal Pd and phosphine ligands. The new protocol requires a nonprecious metal catalyst and has gre...

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Veröffentlicht in:Organic letters 2009-03, Vol.11 (6), p.1321-1324
Hauptverfasser: Liu, Jianming, Zhang, Rongzhao, Wang, Shoufeng, Sun, Wei, Xia, Chungu
Format: Artikel
Sprache:eng
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Zusammenfassung:The use of (NHC)CuI complex in combination with a N-heterocyclic carbene precursor as catalyst for the double carbonylation of aryl Iodides and secondary amines solves the problem of using the precious metal Pd and phosphine ligands. The new protocol requires a nonprecious metal catalyst and has greater generality than those previously reported.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol9001027