A thermal 6pi electrocyclization strategy towards taiwaniaquinoids. First enantiospecific synthesis of (-)-taiwaniaquinone G

A thermal 6pi electrocyclization strategy towards taiwaniaquinoids. First enantiospecific synthesis of (-)-taiwaniaquinone G

The first route towards taiwaniaquinoid terpenes bearing an A/B trans-configuration has been developed through a sequence which includes a thermal 6pi electrocyclization.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2009-02 (5), p.592-594
Hauptverfasser: Alvarez-Manzaneda, Enrique, Chahboun, Rachid, Cabrera, Eduardo, Alvarez, Esteban, Haidour, Ali, Ramos, Jose Miguel, Alvarez-Manzaneda, Ramón, Hmamouchi, Mohammed, Es-Samti, Hakima
Format: Artikel
Sprache:eng
Schlagworte:
Cyclization
Diterpenes - chemical synthesis
Diterpenes - chemistry
Electrons
Stereoisomerism
Temperature
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Zusammenfassung:The first route towards taiwaniaquinoid terpenes bearing an A/B trans-configuration has been developed through a sequence which includes a thermal 6pi electrocyclization.
ISSN:1359-7345
DOI:10.1039/b816812a