Ferrimagnetic [CoII3(micro3-OH)2(RCO2)4] chains embedded in a laminar hybrid material exhibiting single-chain magnet behaviour

Ferrimagnetic [CoII3(micro3-OH)2(RCO2)4] chains embedded in a laminar hybrid material exhibiting single-chain magnet behaviour

The ligand, benzophenone-2,4'-dicarboxylate, was used as a polytopic linker and magnetic separator to bridge the inorganic hydroxide-bridged cobat(ii) chain motifs into a laminar inorganic-organic hybrid materials with nearest inter-chain Co(ii)Co(ii) distance of ca. 8.14 A, which exhibits sing...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2009-01 (11), p.1897-1900
Hauptverfasser: Hu, Sheng, Yun, Lei, Zheng, Yan-Zhen, Lan, Yan-Hua, Powell, Annie K, Tong, Ming-Liang
Format: Artikel
Sprache:eng
Schlagworte:
Cobalt - chemistry
Crystallography, X-Ray
Ligands
Magnetics
Organometallic Compounds - chemistry
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:The ligand, benzophenone-2,4'-dicarboxylate, was used as a polytopic linker and magnetic separator to bridge the inorganic hydroxide-bridged cobat(ii) chain motifs into a laminar inorganic-organic hybrid materials with nearest inter-chain Co(ii)Co(ii) distance of ca. 8.14 A, which exhibits single-chain magnet behaviour.
ISSN:1477-9226
1477-9234
DOI:10.1039/b901163n