Reaction of a Metallamacrocycle Leading to a Mercury(II)···Palladium(II)···Mercury(II) Interaction

Reaction of a Metallamacrocycle Leading to a Mercury(II)···Palladium(II)···Mercury(II) Interaction

All wrapped up: The reaction of a 22-membered macrocycle derived from bis(o-formylphenyl)mercury and 1,2-phenylenediamine with palladium(II) results in cleavage of the macrocycle and concomitant formation of a trimetallic complex (see picture; phenyl rings truncated for clarity). The nature of the H...

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Veröffentlicht in:Angewandte Chemie (International ed.) 2009-03, Vol.48 (11), p.1987-1990
Hauptverfasser: Sharma, Sagar, Baligar, Rajesh S, Singh, Harkesh B, Butcher, Ray J
Format: Artikel
Sprache:eng
Schlagworte:
helical structures
mercury
metallacycles
metal–metal interactions
palladium
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Zusammenfassung:All wrapped up: The reaction of a 22-membered macrocycle derived from bis(o-formylphenyl)mercury and 1,2-phenylenediamine with palladium(II) results in cleavage of the macrocycle and concomitant formation of a trimetallic complex (see picture; phenyl rings truncated for clarity). The nature of the HgII···PdII···HgII interaction was investigated by theoretical studies.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200805121