Development of a Ruthenium-Catalyzed Asymmetric Epoxidation Procedure with Hydrogen Peroxide as the Oxidant

Development of a Ruthenium-Catalyzed Asymmetric Epoxidation Procedure with Hydrogen Peroxide as the Oxidant

Novel pyboxazines and the known pybox ligands are used in the ruthenium‐catalyzed asymmetric epoxidation of olefins with H2O2 (see scheme). This new catalytic system is successful in the conversion of differently substituted aromatic olefins and gives ee values of up to 84 %.

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Angewandte Chemie International Edition 2004-10, Vol.43 (39), p.5255-5260
Hauptverfasser: Tse, Man Kin, Döbler, Christian, Bhor, Santosh, Klawonn, Markus, Mägerlein, Wolfgang, Hugl, Herbert, Beller, Matthias
Format: Artikel
Sprache:eng
Schlagworte:
asymmetric catalysis
epoxidations
homogeneous catalysis
ruthenium
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 5260
container_issue 39
container_start_page 5255
container_title Angewandte Chemie International Edition
container_volume 43
creator Tse, Man Kin
Döbler, Christian
Bhor, Santosh
Klawonn, Markus
Mägerlein, Wolfgang
Hugl, Herbert
Beller, Matthias
description Novel pyboxazines and the known pybox ligands are used in the ruthenium‐catalyzed asymmetric epoxidation of olefins with H2O2 (see scheme). This new catalytic system is successful in the conversion of differently substituted aromatic olefins and gives ee values of up to 84 %.
doi_str_mv 10.1002/anie.200460528
format Article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_66934436</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>66934436</sourcerecordid><originalsourceid>FETCH-LOGICAL-c3798-2fb17286ec4cc97b15d20dfe1a88a93fdc329541df9c4e59a014e82a635141183</originalsourceid><addsrcrecordid>eNqFkEtv1DAURi0EoqWwZYm8YpfBz8RZjsL0IVXTCkG7tDz2DTVN4sF2aNNf34xmVNix8pV1zll8CH2kZEEJYV_M4GHBCBElkUy9QsdUMlrwquKv51twXlRK0iP0LqVfM68UKd-iIyqFlIKJY3T_Ff5AF7Y9DBmHFhv8bcx3MPixLxqTTTc9gcPLNPU95OgtXm3Do3cm-zDg6xgsuDECfvD5Dp9PLoafMP9D3EGATcJzDF_tjCG_R29a0yX4cHhP0I_T1ffmvLi8OrtolpeF5VWtCtZuaMVUCVZYW1cbKh0jrgVqlDI1b53lrJaCura2AmRtCBWgmCm5pIJSxU_Q5313G8PvEVLWvU8Wus4MEMaky7LmQvByBhd70MaQUoRWb6PvTZw0JXo3r97Nq1_mnYVPh_K46cH9xQ97zkC9Bx58B9N_cnq5vlj9Gy_2rk8ZHl9cE-91WfFK6tv1mb5pmhu5vlX6mj8DfZ2XbQ</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>66934436</pqid></control><display><type>article</type><title>Development of a Ruthenium-Catalyzed Asymmetric Epoxidation Procedure with Hydrogen Peroxide as the Oxidant</title><source>Wiley Online Library Journals Frontfile Complete</source><creator>Tse, Man Kin ; Döbler, Christian ; Bhor, Santosh ; Klawonn, Markus ; Mägerlein, Wolfgang ; Hugl, Herbert ; Beller, Matthias</creator><creatorcontrib>Tse, Man Kin ; Döbler, Christian ; Bhor, Santosh ; Klawonn, Markus ; Mägerlein, Wolfgang ; Hugl, Herbert ; Beller, Matthias</creatorcontrib><description>Novel pyboxazines and the known pybox ligands are used in the ruthenium‐catalyzed asymmetric epoxidation of olefins with H2O2 (see scheme). This new catalytic system is successful in the conversion of differently substituted aromatic olefins and gives ee values of up to 84 %.</description><identifier>ISSN: 1433-7851</identifier><identifier>EISSN: 1521-3773</identifier><identifier>DOI: 10.1002/anie.200460528</identifier><identifier>PMID: 15455424</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>asymmetric catalysis ; epoxidations ; homogeneous catalysis ; ruthenium</subject><ispartof>Angewandte Chemie International Edition, 2004-10, Vol.43 (39), p.5255-5260</ispartof><rights>Copyright © 2004 WILEY‐VCH Verlag GmbH &amp; Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3798-2fb17286ec4cc97b15d20dfe1a88a93fdc329541df9c4e59a014e82a635141183</citedby><cites>FETCH-LOGICAL-c3798-2fb17286ec4cc97b15d20dfe1a88a93fdc329541df9c4e59a014e82a635141183</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fanie.200460528$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fanie.200460528$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/15455424$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Tse, Man Kin</creatorcontrib><creatorcontrib>Döbler, Christian</creatorcontrib><creatorcontrib>Bhor, Santosh</creatorcontrib><creatorcontrib>Klawonn, Markus</creatorcontrib><creatorcontrib>Mägerlein, Wolfgang</creatorcontrib><creatorcontrib>Hugl, Herbert</creatorcontrib><creatorcontrib>Beller, Matthias</creatorcontrib><title>Development of a Ruthenium-Catalyzed Asymmetric Epoxidation Procedure with Hydrogen Peroxide as the Oxidant</title><title>Angewandte Chemie International Edition</title><addtitle>Angewandte Chemie International Edition</addtitle><description>Novel pyboxazines and the known pybox ligands are used in the ruthenium‐catalyzed asymmetric epoxidation of olefins with H2O2 (see scheme). This new catalytic system is successful in the conversion of differently substituted aromatic olefins and gives ee values of up to 84 %.</description><subject>asymmetric catalysis</subject><subject>epoxidations</subject><subject>homogeneous catalysis</subject><subject>ruthenium</subject><issn>1433-7851</issn><issn>1521-3773</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2004</creationdate><recordtype>article</recordtype><recordid>eNqFkEtv1DAURi0EoqWwZYm8YpfBz8RZjsL0IVXTCkG7tDz2DTVN4sF2aNNf34xmVNix8pV1zll8CH2kZEEJYV_M4GHBCBElkUy9QsdUMlrwquKv51twXlRK0iP0LqVfM68UKd-iIyqFlIKJY3T_Ff5AF7Y9DBmHFhv8bcx3MPixLxqTTTc9gcPLNPU95OgtXm3Do3cm-zDg6xgsuDECfvD5Dp9PLoafMP9D3EGATcJzDF_tjCG_R29a0yX4cHhP0I_T1ffmvLi8OrtolpeF5VWtCtZuaMVUCVZYW1cbKh0jrgVqlDI1b53lrJaCura2AmRtCBWgmCm5pIJSxU_Q5313G8PvEVLWvU8Wus4MEMaky7LmQvByBhd70MaQUoRWb6PvTZw0JXo3r97Nq1_mnYVPh_K46cH9xQ97zkC9Bx58B9N_cnq5vlj9Gy_2rk8ZHl9cE-91WfFK6tv1mb5pmhu5vlX6mj8DfZ2XbQ</recordid><startdate>20041004</startdate><enddate>20041004</enddate><creator>Tse, Man Kin</creator><creator>Döbler, Christian</creator><creator>Bhor, Santosh</creator><creator>Klawonn, Markus</creator><creator>Mägerlein, Wolfgang</creator><creator>Hugl, Herbert</creator><creator>Beller, Matthias</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><scope>BSCLL</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20041004</creationdate><title>Development of a Ruthenium-Catalyzed Asymmetric Epoxidation Procedure with Hydrogen Peroxide as the Oxidant</title><author>Tse, Man Kin ; Döbler, Christian ; Bhor, Santosh ; Klawonn, Markus ; Mägerlein, Wolfgang ; Hugl, Herbert ; Beller, Matthias</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3798-2fb17286ec4cc97b15d20dfe1a88a93fdc329541df9c4e59a014e82a635141183</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2004</creationdate><topic>asymmetric catalysis</topic><topic>epoxidations</topic><topic>homogeneous catalysis</topic><topic>ruthenium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Tse, Man Kin</creatorcontrib><creatorcontrib>Döbler, Christian</creatorcontrib><creatorcontrib>Bhor, Santosh</creatorcontrib><creatorcontrib>Klawonn, Markus</creatorcontrib><creatorcontrib>Mägerlein, Wolfgang</creatorcontrib><creatorcontrib>Hugl, Herbert</creatorcontrib><creatorcontrib>Beller, Matthias</creatorcontrib><collection>Istex</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Angewandte Chemie International Edition</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Tse, Man Kin</au><au>Döbler, Christian</au><au>Bhor, Santosh</au><au>Klawonn, Markus</au><au>Mägerlein, Wolfgang</au><au>Hugl, Herbert</au><au>Beller, Matthias</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Development of a Ruthenium-Catalyzed Asymmetric Epoxidation Procedure with Hydrogen Peroxide as the Oxidant</atitle><jtitle>Angewandte Chemie International Edition</jtitle><addtitle>Angewandte Chemie International Edition</addtitle><date>2004-10-04</date><risdate>2004</risdate><volume>43</volume><issue>39</issue><spage>5255</spage><epage>5260</epage><pages>5255-5260</pages><issn>1433-7851</issn><eissn>1521-3773</eissn><abstract>Novel pyboxazines and the known pybox ligands are used in the ruthenium‐catalyzed asymmetric epoxidation of olefins with H2O2 (see scheme). This new catalytic system is successful in the conversion of differently substituted aromatic olefins and gives ee values of up to 84 %.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><pmid>15455424</pmid><doi>10.1002/anie.200460528</doi><tpages>6</tpages></addata></record>
fulltext fulltext
identifier ISSN: 1433-7851
ispartof Angewandte Chemie International Edition, 2004-10, Vol.43 (39), p.5255-5260
issn 1433-7851
1521-3773
language eng
recordid cdi_proquest_miscellaneous_66934436
source Wiley Online Library Journals Frontfile Complete
subjects asymmetric catalysis
epoxidations
homogeneous catalysis
ruthenium
title Development of a Ruthenium-Catalyzed Asymmetric Epoxidation Procedure with Hydrogen Peroxide as the Oxidant
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-08T02%3A49%3A16IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Development%20of%20a%20Ruthenium-Catalyzed%20Asymmetric%20Epoxidation%20Procedure%20with%20Hydrogen%20Peroxide%20as%20the%20Oxidant&rft.jtitle=Angewandte%20Chemie%20International%20Edition&rft.au=Tse,%20Man%20Kin&rft.date=2004-10-04&rft.volume=43&rft.issue=39&rft.spage=5255&rft.epage=5260&rft.pages=5255-5260&rft.issn=1433-7851&rft.eissn=1521-3773&rft_id=info:doi/10.1002/anie.200460528&rft_dat=%3Cproquest_cross%3E66934436%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=66934436&rft_id=info:pmid/15455424&rfr_iscdi=true