Rigid and Flexible: A Highly Porous Metal-Organic Framework with Unusual Guest-Dependent Dynamic Behavior
A large H2 sorption capacity and high surface area are properties of the depicted metal–organic porous material, which is easily synthesized on a large scale from readily available chemicals. The rigid framework of [Zn2(1,4‐bdc)2(dabco)] (1,4‐H2bdc=1,4‐benzenedicarboxylic acid; dabco=diazabicyclo[2....
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| Veröffentlicht in: | Angewandte Chemie International Edition 2004-09, Vol.43 (38), p.5033-5036 |
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| container_title | Angewandte Chemie International Edition |
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| creator | Dybtsev, Danil N. Chun, Hyungphil Kim, Kimoon |
| description | A large H2 sorption capacity and high surface area are properties of the depicted metal–organic porous material, which is easily synthesized on a large scale from readily available chemicals. The rigid framework of [Zn2(1,4‐bdc)2(dabco)] (1,4‐H2bdc=1,4‐benzenedicarboxylic acid; dabco=diazabicyclo[2.2.2]octane) is also flexible enough to exhibit unusual guest‐dependent dynamic behavior, as shown (DMF=N,N‐dimethylformamide). |
| doi_str_mv | 10.1002/anie.200460712 |
| format | Article |
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| subjects | carboxylate ligands coordination polymers Crystallography, X-Ray gas sorption host-guest systems Models, Molecular Molecular Structure Organometallic Compounds - chemistry Porosity Thermodynamics Zinc - chemistry |
| title | Rigid and Flexible: A Highly Porous Metal-Organic Framework with Unusual Guest-Dependent Dynamic Behavior |
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