Rigid and Flexible: A Highly Porous Metal-Organic Framework with Unusual Guest-Dependent Dynamic Behavior

Rigid and Flexible: A Highly Porous Metal-Organic Framework with Unusual Guest-Dependent Dynamic Behavior

A large H2 sorption capacity and high surface area are properties of the depicted metal–organic porous material, which is easily synthesized on a large scale from readily available chemicals. The rigid framework of [Zn2(1,4‐bdc)2(dabco)] (1,4‐H2bdc=1,4‐benzenedicarboxylic acid; dabco=diazabicyclo[2....

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Veröffentlicht in:Angewandte Chemie International Edition 2004-09, Vol.43 (38), p.5033-5036
Hauptverfasser: Dybtsev, Danil N., Chun, Hyungphil, Kim, Kimoon
Format: Artikel
Sprache:eng
Schlagworte:
carboxylate ligands
coordination polymers
Crystallography, X-Ray
gas sorption
host-guest systems
Models, Molecular
Molecular Structure
Organometallic Compounds - chemistry
Porosity
Thermodynamics
Zinc - chemistry
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Beschreibung
Zusammenfassung:A large H2 sorption capacity and high surface area are properties of the depicted metal–organic porous material, which is easily synthesized on a large scale from readily available chemicals. The rigid framework of [Zn2(1,4‐bdc)2(dabco)] (1,4‐H2bdc=1,4‐benzenedicarboxylic acid; dabco=diazabicyclo[2.2.2]octane) is also flexible enough to exhibit unusual guest‐dependent dynamic behavior, as shown (DMF=N,N‐dimethylformamide).
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200460712