On the Way to "Solid Nitrogen" at Normal Temperature and Pressure? Binary Azides of Heavier Group 15 and 16 Elements

On the Way to "Solid Nitrogen" at Normal Temperature and Pressure? Binary Azides of Heavier Group 15 and 16 Elements

Caution explosive! Homoleptic azides are of great interest as polynitrogen compounds particularly because of their high energy content. A recent breakthrough is the first synthesis and characterization of the highly sensitive neutral tellurium azide [Te(N3)4] and of ionic (N5)+[P(N3)6]− containing 2...

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Veröffentlicht in:Angewandte Chemie International Edition 2004-09, Vol.43 (37), p.4834-4836
Hauptverfasser: Knapp, Carsten, Passmore, Jack
Format: Artikel
Sprache:eng
Schlagworte:
azides
Group 15 elements
hazardous materials
high-energy materials
polynitrogen compounds
selenium
tellurium
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Zusammenfassung:Caution explosive! Homoleptic azides are of great interest as polynitrogen compounds particularly because of their high energy content. A recent breakthrough is the first synthesis and characterization of the highly sensitive neutral tellurium azide [Te(N3)4] and of ionic (N5)+[P(N3)6]− containing 23 nitrogen atoms.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200401748