Structure and Phase Behavior of the Expanded‐Metal Compound 7Li(ND3)4

Metal lite: High‐resolution neutron powder diffraction data reveals that the body‐centered cubic crystal structure of lithium(0)tetraamine transforms to a simple cubic structure below 22 K. The detailed structure determinations will allow new insights into the coupled structural and electronic prope...

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Veröffentlicht in:Angewandte Chemie International Edition 2009, Vol.48 (8), p.1435-1438
Hauptverfasser: Ibberson, Richard M., Fowkes, Amelia J., Rosseinsky, Matthew J., David, William I. F., Edwards, Peter P.
Format: Artikel
Sprache:eng
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Zusammenfassung:Metal lite: High‐resolution neutron powder diffraction data reveals that the body‐centered cubic crystal structure of lithium(0)tetraamine transforms to a simple cubic structure below 22 K. The detailed structure determinations will allow new insights into the coupled structural and electronic properties of the lightest metal. Metal lite: High‐resolution neutron powder diffraction data reveals that the body‐centered cubic crystal structure of lithium(0)tetraamine transforms to a simple cubic structure below 22 K. The detailed structure determinations will allow new insights into the coupled structural and electronic properties of the lightest metal.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200804339