Intramolecular exchange interaction in twofold spin-labelled platinum complexes

The synthesis and the crystal structures of two platinum bis-ethynyl-phenyl-nitronyl-nitroxide complexes are reported and solution EPR investigations evidenced the intramolecular exchange interaction through a diamagnetic transition metal based spacer.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2004-09 (18), p.2050-2051
Hauptverfasser: Stroh, Christophe, Mayor, Marcel, von Hanisch, Carsten, Turek, Philippe
Format: Artikel
Sprache:eng
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Zusammenfassung:The synthesis and the crystal structures of two platinum bis-ethynyl-phenyl-nitronyl-nitroxide complexes are reported and solution EPR investigations evidenced the intramolecular exchange interaction through a diamagnetic transition metal based spacer.
ISSN:1359-7345
1364-548X
DOI:10.1039/b407067d