The synthesis of unsymmetrically N-substituted chiral 1,4,7-triazacyclononanes

The synthesis of unsymmetrically N-substituted chiral 1,4,7-triazacyclononanes

A number of chiral unsymmetrically N-substituted 1,4,7-triazacyclononane ligands have been prepared by modular methods. The key step in the synthesis centres on the macrocyclisation of three tertiary amide precursors under standard Richman-Atkins conditions which allows for subsequent N-functionalis...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Organic & biomolecular chemistry 2004-09, Vol.2 (18), p.2664-2670
Hauptverfasser: Scheuermann, J Erik W, Sibbons, Kevin F, Benoit, David M, Motevalli, Majid, Watkinson, Michael
Format: Artikel
Sprache:eng
Schlagworte:
Catalysis
Crystallography, X-Ray
Heterocyclic Compounds - chemical synthesis
Heterocyclic Compounds - chemistry
Ligands
Molecular Structure
Oxidation-Reduction
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:A number of chiral unsymmetrically N-substituted 1,4,7-triazacyclononane ligands have been prepared by modular methods. The key step in the synthesis centres on the macrocyclisation of three tertiary amide precursors under standard Richman-Atkins conditions which allows for subsequent N-functionalisation.
ISSN:1477-0520
1477-0539
DOI:10.1039/b409259g