Highly Active Dizinc Catalyst for the Copolymerization of Carbon Dioxide and Cyclohexene Oxide at One Atmosphere Pressure
Low‐pressure catalyst: A novel dizinc complex (1) having a macrocyclic ancillary ligand shows remarkable activity for the copolymerization of carbon dioxide and cyclohexene oxide, at only one atmosphere of CO2. TON=turnover number; TOF=turnover frequency.
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Veröffentlicht in: | Angewandte Chemie (International ed.) 2009-01, Vol.48 (5), p.931-933 |
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creator | Kember, Michael R Knight, Paul D Reung, Palarp T.R Williams, Charlotte K |
description | Low‐pressure catalyst: A novel dizinc complex (1) having a macrocyclic ancillary ligand shows remarkable activity for the copolymerization of carbon dioxide and cyclohexene oxide, at only one atmosphere of CO2. TON=turnover number; TOF=turnover frequency. |
doi_str_mv | 10.1002/anie.200803896 |
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language | eng |
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source | MEDLINE; Wiley Online Library |
subjects | Atmospheric Pressure carbon dioxide Carbon Dioxide - chemistry Catalysis Cyclohexenes - chemistry macrocyclic ligands Molecular Structure Organometallic Compounds - chemical synthesis Organometallic Compounds - chemistry polymerization Polymers - chemical synthesis Polymers - chemistry zinc Zinc - chemistry |
title | Highly Active Dizinc Catalyst for the Copolymerization of Carbon Dioxide and Cyclohexene Oxide at One Atmosphere Pressure |
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