Highly Active Dizinc Catalyst for the Copolymerization of Carbon Dioxide and Cyclohexene Oxide at One Atmosphere Pressure

Highly Active Dizinc Catalyst for the Copolymerization of Carbon Dioxide and Cyclohexene Oxide at One Atmosphere Pressure

Low‐pressure catalyst: A novel dizinc complex (1) having a macrocyclic ancillary ligand shows remarkable activity for the copolymerization of carbon dioxide and cyclohexene oxide, at only one atmosphere of CO2. TON=turnover number; TOF=turnover frequency.

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Veröffentlicht in:Angewandte Chemie (International ed.) 2009-01, Vol.48 (5), p.931-933
Hauptverfasser: Kember, Michael R, Knight, Paul D, Reung, Palarp T.R, Williams, Charlotte K
Format: Artikel
Sprache:eng
Schlagworte:
Atmospheric Pressure
carbon dioxide
Carbon Dioxide - chemistry
Catalysis
Cyclohexenes - chemistry
macrocyclic ligands
Molecular Structure
Organometallic Compounds - chemical synthesis
Organometallic Compounds - chemistry
polymerization
Polymers - chemical synthesis
Polymers - chemistry
zinc
Zinc - chemistry
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Beschreibung
Zusammenfassung:Low‐pressure catalyst: A novel dizinc complex (1) having a macrocyclic ancillary ligand shows remarkable activity for the copolymerization of carbon dioxide and cyclohexene oxide, at only one atmosphere of CO2. TON=turnover number; TOF=turnover frequency.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200803896