Asymmetric Synthesis Utilizing Circularly Polarized Light Mediated by the Photoequilibrium of Chiral Olefins in Conjunction with Asymmetric Autocatalysis

The light touch: Asymmetric photoequilibrium and autocatalysis act as sources of homochirality in a highly enantioselective preparation of chiral alcohols (see scheme). This process is initiated by left‐ and right‐circularly polarized light (CPL) and exploits the resulting photoequilibrium between c...

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Veröffentlicht in:	Angewandte Chemie International Edition 2004-08, Vol.43 (34), p.4490-4492
Hauptverfasser:	Sato, Itaru, Sugie, Rie, Matsueda, Yohei, Furumura, Yuri, Soai, Kenso
Format:	Artikel
Sprache:	eng
Schlagworte:	alkenes asymmetric amplification asymmetric catalysis autocatalysis chirality
Online-Zugang:	Volltext
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