Asymmetric Synthesis Utilizing Circularly Polarized Light Mediated by the Photoequilibrium of Chiral Olefins in Conjunction with Asymmetric Autocatalysis
The light touch: Asymmetric photoequilibrium and autocatalysis act as sources of homochirality in a highly enantioselective preparation of chiral alcohols (see scheme). This process is initiated by left‐ and right‐circularly polarized light (CPL) and exploits the resulting photoequilibrium between c...
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| Veröffentlicht in: | Angewandte Chemie International Edition 2004-08, Vol.43 (34), p.4490-4492 |
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| container_end_page | 4492 |
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| container_issue | 34 |
| container_start_page | 4490 |
| container_title | Angewandte Chemie International Edition |
| container_volume | 43 |
| creator | Sato, Itaru Sugie, Rie Matsueda, Yohei Furumura, Yuri Soai, Kenso |
| description | The light touch: Asymmetric photoequilibrium and autocatalysis act as sources of homochirality in a highly enantioselective preparation of chiral alcohols (see scheme). This process is initiated by left‐ and right‐circularly polarized light (CPL) and exploits the resulting photoequilibrium between chiral olefin substrates to yield 2‐alkynyl‐5‐pyrimidyl alkanols. |
| doi_str_mv | 10.1002/anie.200454162 |
| format | Article |
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| language | eng |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | alkenes asymmetric amplification asymmetric catalysis autocatalysis chirality |
| title | Asymmetric Synthesis Utilizing Circularly Polarized Light Mediated by the Photoequilibrium of Chiral Olefins in Conjunction with Asymmetric Autocatalysis |
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