Triaryl Boron-Based A-π-A vs Triaryl Nitrogen-Based D-π-D Quadrupolar Compounds for Single- and Two-Photon Excited Fluorescence

Three new A-π-A-type compounds with trivalent boron, protected by two mesityl groups, as electron acceptor have been synthesized and investigated together with their two diphenylamino-ended D-π-D analogues. These boranes exhibit large two-photon absorption cross sections and high fluorescence quantu...

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Veröffentlicht in:Organic letters 2004-08, Vol.6 (17), p.2933-2936
Hauptverfasser: Liu, Zhi-Qiang, Fang, Qi, Cao, Du-Xia, Wang, Dong, Xu, Gui-Bao
Format: Artikel
Sprache:eng
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Zusammenfassung:Three new A-π-A-type compounds with trivalent boron, protected by two mesityl groups, as electron acceptor have been synthesized and investigated together with their two diphenylamino-ended D-π-D analogues. These boranes exhibit large two-photon absorption cross sections and high fluorescence quantum yields.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol048984a