Tunable coordination of a tropos phosphite for fine-tuning of the Rh catalyzed asymmetric addition of phenylboronic acid to cyclohexenone

Tunable coordination of a tropos phosphite for fine-tuning of the Rh catalyzed asymmetric addition of phenylboronic acid to cyclohexenone

Using the deoxycholic acid derived tropos biphenylphosphite as a Rh(i) chiral ligand different complexes are obtained, depending on the Rh : L molar ratio, that give rise to the formation of different chiral products in the asymmetric addition of phenylboronic acid to cyclohexenone.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2009-01 (4), p.457-459
Hauptverfasser: Iuliano, Anna, Facchetti, Sarah, Funaioli, Tiziana
Format: Artikel
Sprache:eng
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Zusammenfassung:Using the deoxycholic acid derived tropos biphenylphosphite as a Rh(i) chiral ligand different complexes are obtained, depending on the Rh : L molar ratio, that give rise to the formation of different chiral products in the asymmetric addition of phenylboronic acid to cyclohexenone.
ISSN:1359-7345
DOI:10.1039/b814568g