Rigidity extremes in coordination chemistry: a fine energetic balance in the isolation of a trapped ligand inversion intermediate

Rigidity extremes in coordination chemistry: a fine energetic balance in the isolation of a trapped ligand inversion intermediate

An unusual copper(ii) complex of a highly rigid and bulky ligand (a macrocycle-glyoxal condensate) has been synthesized and investigated via DFT calculations and structural characterisation.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2004-08 (16), p.1880-1881
Hauptverfasser: May, Caleb M, Archibald, Stephen J, Bridgeman, Adam J, Empson, Christopher J, Hubin, Timothy J
Format: Artikel
Sprache:eng
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Zusammenfassung:An unusual copper(ii) complex of a highly rigid and bulky ligand (a macrocycle-glyoxal condensate) has been synthesized and investigated via DFT calculations and structural characterisation.
ISSN:1359-7345
DOI:10.1039/b405358c