Palladium-Catalyzed Enantioselective Ring Opening of Oxabicyclic Alkenes with Organozinc Halides

Palladium-Catalyzed Enantioselective Ring Opening of Oxabicyclic Alkenes with Organozinc Halides

Palladium-catalyzed asymmetric ring opening of oxabenzonorbornadienes with readily available organozinc halides under mild conditions in the presence of (S)-Pr i -PHOX produces the corresponding 1,2-dihydronaphth-1-ols in good yield and high enantioselectivity.

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Veröffentlicht in:Organic letters 2004-08, Vol.6 (16), p.2833-2835
Hauptverfasser: Li, Ming, Yan, Xiao-Xia, Hong, Wei, Zhu, Xia-Zhen, Cao, Bo-Xun, Sun, Jie, Hou, Xue-Long
Format: Artikel
Sprache:eng
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Zusammenfassung:Palladium-catalyzed asymmetric ring opening of oxabenzonorbornadienes with readily available organozinc halides under mild conditions in the presence of (S)-Pr i -PHOX produces the corresponding 1,2-dihydronaphth-1-ols in good yield and high enantioselectivity.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol048816i