A preconcentrator coupled to a GC/FTMS: advantages of self-chemical ionization, mass measurement accuracy, and high mass resolving power for GC applications
Coupling of a cryogenic preconcentrator (PC) to a gas chromatograph/Fourier transform ion cyclotron resonance mass spectrometer (GC/FT-ICR MS) is reported. To demonstrate the analytical capabilities of the PC/GC/FT-ICR MS, headspace samples containing volatile organic compounds (VOCs) emitted from d...
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| Veröffentlicht in: | Journal of the American Society for Mass Spectrometry 2004-08, Vol.15 (8), p.1191-1200 |
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| creator | Solouki, Touradj Szulejko, Jan E. Bennett, Justin B. Graham, LeRae B. |
| description | Coupling of a cryogenic preconcentrator (PC) to a gas chromatograph/Fourier transform ion cyclotron resonance mass spectrometer (GC/FT-ICR MS) is reported. To demonstrate the analytical capabilities of the PC/GC/FT-ICR MS, headspace samples containing volatile organic compounds (VOCs) emitted from detached pine tree twigs were analyzed. Sub-ppm mass measurement accuracy (MMA) for highly resolved (m/Δm
50% > 150 k) terpene ions was achieved. Direct PC/GC/FT-ICR MS analyses revealed that detached twigs from pine trees emit acetone, camphor, and four detectable hydrocarbon isomers with C
10H
16 empirical formula. The unknown analytes were identified based on accurate mass measurement and their mass spectral appearances. Authentic samples were used to confirm initially unknown identifications. Self-chemical-ionization (SCI) reactions furnished an additional dimension for rapid isomer differentiation of GC eluents in real time. |
| doi_str_mv | 10.1016/j.jasms.2004.03.003 |
| format | Article |
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50% > 150 k) terpene ions was achieved. Direct PC/GC/FT-ICR MS analyses revealed that detached twigs from pine trees emit acetone, camphor, and four detectable hydrocarbon isomers with C
10H
16 empirical formula. The unknown analytes were identified based on accurate mass measurement and their mass spectral appearances. Authentic samples were used to confirm initially unknown identifications. Self-chemical-ionization (SCI) reactions furnished an additional dimension for rapid isomer differentiation of GC eluents in real time.</description><identifier>ISSN: 1044-0305</identifier><identifier>EISSN: 1879-1123</identifier><identifier>DOI: 10.1016/j.jasms.2004.03.003</identifier><identifier>PMID: 15276166</identifier><language>eng</language><publisher>New York, NY: Elsevier Inc</publisher><subject>Acetone ; Analytical chemistry ; Biological and medical sciences ; Camphor ; Chemical constitution ; Chemical reactions ; Chemistry ; Chromatographic methods and physical methods associated with chromatography ; Coupling (molecular) ; Cyclotron resonance ; Cyclotrons ; Eluents ; Empirical analysis ; Exact sciences and technology ; Flame Ionization ; Fourier transforms ; Fundamental and applied biological sciences. Psychology ; Gas chromatographic methods ; Gas chromatography ; Gas Chromatography-Mass Spectrometry - methods ; Hydrocarbons - analysis ; Ionization ; Ions ; Isomers ; Mass spectrometry ; Molecular Weight ; Organic compounds ; Pine ; Pinus - chemistry ; Plant physiology and development ; Polymethyl methacrylate ; Reproducibility of Results ; Resolution ; Spectroscopy, Fourier Transform Infrared ; VOCs ; Volatile organic compounds ; Volatilization ; Wood</subject><ispartof>Journal of the American Society for Mass Spectrometry, 2004-08, Vol.15 (8), p.1191-1200</ispartof><rights>2004 American Society for Mass Spectrometry</rights><rights>2005 INIST-CNRS</rights><rights>American Society for Mass Spectrometry 2004</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c458t-8d8e5489c8d05dbc9dc8ce602b0721510d55faadc788775f0e0a63e7c18fcc613</citedby><cites>FETCH-LOGICAL-c458t-8d8e5489c8d05dbc9dc8ce602b0721510d55faadc788775f0e0a63e7c18fcc613</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27923,27924</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=16014655$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/15276166$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Solouki, Touradj</creatorcontrib><creatorcontrib>Szulejko, Jan E.</creatorcontrib><creatorcontrib>Bennett, Justin B.</creatorcontrib><creatorcontrib>Graham, LeRae B.</creatorcontrib><title>A preconcentrator coupled to a GC/FTMS: advantages of self-chemical ionization, mass measurement accuracy, and high mass resolving power for GC applications</title><title>Journal of the American Society for Mass Spectrometry</title><addtitle>J Am Soc Mass Spectrom</addtitle><description>Coupling of a cryogenic preconcentrator (PC) to a gas chromatograph/Fourier transform ion cyclotron resonance mass spectrometer (GC/FT-ICR MS) is reported. To demonstrate the analytical capabilities of the PC/GC/FT-ICR MS, headspace samples containing volatile organic compounds (VOCs) emitted from detached pine tree twigs were analyzed. Sub-ppm mass measurement accuracy (MMA) for highly resolved (m/Δm
50% > 150 k) terpene ions was achieved. Direct PC/GC/FT-ICR MS analyses revealed that detached twigs from pine trees emit acetone, camphor, and four detectable hydrocarbon isomers with C
10H
16 empirical formula. The unknown analytes were identified based on accurate mass measurement and their mass spectral appearances. Authentic samples were used to confirm initially unknown identifications. Self-chemical-ionization (SCI) reactions furnished an additional dimension for rapid isomer differentiation of GC eluents in real time.</description><subject>Acetone</subject><subject>Analytical chemistry</subject><subject>Biological and medical sciences</subject><subject>Camphor</subject><subject>Chemical constitution</subject><subject>Chemical reactions</subject><subject>Chemistry</subject><subject>Chromatographic methods and physical methods associated with chromatography</subject><subject>Coupling (molecular)</subject><subject>Cyclotron resonance</subject><subject>Cyclotrons</subject><subject>Eluents</subject><subject>Empirical analysis</subject><subject>Exact sciences and technology</subject><subject>Flame Ionization</subject><subject>Fourier transforms</subject><subject>Fundamental and applied biological sciences. Psychology</subject><subject>Gas chromatographic methods</subject><subject>Gas chromatography</subject><subject>Gas Chromatography-Mass Spectrometry - methods</subject><subject>Hydrocarbons - analysis</subject><subject>Ionization</subject><subject>Ions</subject><subject>Isomers</subject><subject>Mass spectrometry</subject><subject>Molecular Weight</subject><subject>Organic compounds</subject><subject>Pine</subject><subject>Pinus - chemistry</subject><subject>Plant physiology and development</subject><subject>Polymethyl methacrylate</subject><subject>Reproducibility of Results</subject><subject>Resolution</subject><subject>Spectroscopy, Fourier Transform Infrared</subject><subject>VOCs</subject><subject>Volatile organic compounds</subject><subject>Volatilization</subject><subject>Wood</subject><issn>1044-0305</issn><issn>1879-1123</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2004</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><sourceid>8G5</sourceid><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><sourceid>GUQSH</sourceid><sourceid>M2O</sourceid><recordid>eNp9kcFu1DAQhiMEoqXwBEjIEoJTsx0nsZ2txKFa0QWpiAPlbM3ak11HSRzsZFF5Fh4WL7tSJQ6cxodvfv-aL8tec1hw4PKqXbQY-7goAKoFlAuA8kl2zmu1zDkvyqfpDVWVQwniLHsRYwvAFSzV8-yMi0JJLuV59vuGjYGMHwwNU8DJB2b8PHZk2eQZsvXq6vb-y7drhnaPw4Rbisw3LFLX5GZHvTPYMecH9wunNC5ZjzGynjDOgfqUydCYOaB5uGQ4WLZz292RCRR9t3fDlo3-JwXWpK_XK4bj2KXQQ1h8mT1rsIv06jQvsu-3H-9Xn_K7r-vPq5u73FSinvLa1iSqemlqC8JuzNKa2pCEYgOq4IKDFaJBtEbVtVKiAQKUJSnD68YYycuL7P0xdwz-x0xx0r2LhroOB_Jz1FKqqlSlSODbf8DWz2FI3TRfiqKqFChIVHmkTPAxBmr0GFyP4UFz0Ad1utV_1emDOg2lTurS1ptT9rzpyT7unFwl4N0JwJiu3gQcjIuPnAReSXEo-eHIUTrZ3lHQ0ThKgq1LpidtvftvkT-DP7nK</recordid><startdate>20040801</startdate><enddate>20040801</enddate><creator>Solouki, Touradj</creator><creator>Szulejko, Jan E.</creator><creator>Bennett, Justin B.</creator><creator>Graham, LeRae B.</creator><general>Elsevier Inc</general><general>Elsevier Science</general><general>Springer Nature B.V</general><scope>6I.</scope><scope>AAFTH</scope><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7X7</scope><scope>7XB</scope><scope>88E</scope><scope>8FE</scope><scope>8FG</scope><scope>8FI</scope><scope>8FJ</scope><scope>8FK</scope><scope>8G5</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>ARAPS</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>FYUFA</scope><scope>GHDGH</scope><scope>GNUQQ</scope><scope>GUQSH</scope><scope>HCIFZ</scope><scope>K9.</scope><scope>M0S</scope><scope>M1P</scope><scope>M2O</scope><scope>MBDVC</scope><scope>P5Z</scope><scope>P62</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>Q9U</scope><scope>7X8</scope></search><sort><creationdate>20040801</creationdate><title>A preconcentrator coupled to a GC/FTMS: advantages of self-chemical ionization, mass measurement accuracy, and high mass resolving power for GC applications</title><author>Solouki, Touradj ; Szulejko, Jan E. ; Bennett, Justin B. ; Graham, LeRae B.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c458t-8d8e5489c8d05dbc9dc8ce602b0721510d55faadc788775f0e0a63e7c18fcc613</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2004</creationdate><topic>Acetone</topic><topic>Analytical chemistry</topic><topic>Biological and medical sciences</topic><topic>Camphor</topic><topic>Chemical constitution</topic><topic>Chemical reactions</topic><topic>Chemistry</topic><topic>Chromatographic methods and physical methods associated with chromatography</topic><topic>Coupling (molecular)</topic><topic>Cyclotron resonance</topic><topic>Cyclotrons</topic><topic>Eluents</topic><topic>Empirical analysis</topic><topic>Exact sciences and technology</topic><topic>Flame Ionization</topic><topic>Fourier transforms</topic><topic>Fundamental and applied biological sciences. Psychology</topic><topic>Gas chromatographic methods</topic><topic>Gas chromatography</topic><topic>Gas Chromatography-Mass Spectrometry - methods</topic><topic>Hydrocarbons - analysis</topic><topic>Ionization</topic><topic>Ions</topic><topic>Isomers</topic><topic>Mass spectrometry</topic><topic>Molecular Weight</topic><topic>Organic compounds</topic><topic>Pine</topic><topic>Pinus - chemistry</topic><topic>Plant physiology and development</topic><topic>Polymethyl methacrylate</topic><topic>Reproducibility of Results</topic><topic>Resolution</topic><topic>Spectroscopy, Fourier Transform Infrared</topic><topic>VOCs</topic><topic>Volatile organic compounds</topic><topic>Volatilization</topic><topic>Wood</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Solouki, Touradj</creatorcontrib><creatorcontrib>Szulejko, Jan E.</creatorcontrib><creatorcontrib>Bennett, Justin B.</creatorcontrib><creatorcontrib>Graham, LeRae B.</creatorcontrib><collection>ScienceDirect Open Access Titles</collection><collection>Elsevier:ScienceDirect:Open Access</collection><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>Health & Medical Collection</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Medical Database (Alumni Edition)</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Hospital Premium Collection</collection><collection>Hospital Premium Collection (Alumni Edition)</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>Research Library (Alumni Edition)</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>Advanced Technologies & Aerospace Collection</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Central Korea</collection><collection>Health Research Premium Collection</collection><collection>Health Research Premium Collection (Alumni)</collection><collection>ProQuest Central Student</collection><collection>Research Library Prep</collection><collection>SciTech Premium Collection</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>Health & Medical Collection (Alumni Edition)</collection><collection>Medical Database</collection><collection>Research Library</collection><collection>Research Library (Corporate)</collection><collection>Advanced Technologies & Aerospace Database</collection><collection>ProQuest Advanced Technologies & Aerospace Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central Basic</collection><collection>MEDLINE - Academic</collection><jtitle>Journal of the American Society for Mass Spectrometry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Solouki, Touradj</au><au>Szulejko, Jan E.</au><au>Bennett, Justin B.</au><au>Graham, LeRae B.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A preconcentrator coupled to a GC/FTMS: advantages of self-chemical ionization, mass measurement accuracy, and high mass resolving power for GC applications</atitle><jtitle>Journal of the American Society for Mass Spectrometry</jtitle><addtitle>J Am Soc Mass Spectrom</addtitle><date>2004-08-01</date><risdate>2004</risdate><volume>15</volume><issue>8</issue><spage>1191</spage><epage>1200</epage><pages>1191-1200</pages><issn>1044-0305</issn><eissn>1879-1123</eissn><abstract>Coupling of a cryogenic preconcentrator (PC) to a gas chromatograph/Fourier transform ion cyclotron resonance mass spectrometer (GC/FT-ICR MS) is reported. To demonstrate the analytical capabilities of the PC/GC/FT-ICR MS, headspace samples containing volatile organic compounds (VOCs) emitted from detached pine tree twigs were analyzed. Sub-ppm mass measurement accuracy (MMA) for highly resolved (m/Δm
50% > 150 k) terpene ions was achieved. Direct PC/GC/FT-ICR MS analyses revealed that detached twigs from pine trees emit acetone, camphor, and four detectable hydrocarbon isomers with C
10H
16 empirical formula. The unknown analytes were identified based on accurate mass measurement and their mass spectral appearances. Authentic samples were used to confirm initially unknown identifications. Self-chemical-ionization (SCI) reactions furnished an additional dimension for rapid isomer differentiation of GC eluents in real time.</abstract><cop>New York, NY</cop><pub>Elsevier Inc</pub><pmid>15276166</pmid><doi>10.1016/j.jasms.2004.03.003</doi><tpages>10</tpages><oa>free_for_read</oa></addata></record> |
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| ispartof | Journal of the American Society for Mass Spectrometry, 2004-08, Vol.15 (8), p.1191-1200 |
| issn | 1044-0305 1879-1123 |
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| source | MEDLINE; Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals; Alma/SFX Local Collection; Free Full-Text Journals in Chemistry; SpringerLink Journals - AutoHoldings |
| subjects | Acetone Analytical chemistry Biological and medical sciences Camphor Chemical constitution Chemical reactions Chemistry Chromatographic methods and physical methods associated with chromatography Coupling (molecular) Cyclotron resonance Cyclotrons Eluents Empirical analysis Exact sciences and technology Flame Ionization Fourier transforms Fundamental and applied biological sciences. Psychology Gas chromatographic methods Gas chromatography Gas Chromatography-Mass Spectrometry - methods Hydrocarbons - analysis Ionization Ions Isomers Mass spectrometry Molecular Weight Organic compounds Pine Pinus - chemistry Plant physiology and development Polymethyl methacrylate Reproducibility of Results Resolution Spectroscopy, Fourier Transform Infrared VOCs Volatile organic compounds Volatilization Wood |
| title | A preconcentrator coupled to a GC/FTMS: advantages of self-chemical ionization, mass measurement accuracy, and high mass resolving power for GC applications |
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