First example of an enantiopure planar chiral ligand built on a (eta5-cyclohexadienyl)Mn(CO)3 scaffold

First example of an enantiopure planar chiral ligand built on a (eta5-cyclohexadienyl)Mn(CO)3 scaffold

The synthesis of (eta5-cyclohexadienyl)Mn(CO)3-based planar chiral ligands is realized by an efficient lithiation/electrophilic quench procedure, and the coordinating properties of one of them are highlighted together with its optical resolution.

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2009-01 (1), p.27-29
Hauptverfasser: Cetiner, Derya, Jacques, Béatrice, Payet, Elina, Chavarot-Kerlidou, Murielle, Rose-Munch, Françoise, Rose, Eric, Tranchier, Jean-Philippe, Herson, Patrick
Format: Artikel
Sprache:eng
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Zusammenfassung:The synthesis of (eta5-cyclohexadienyl)Mn(CO)3-based planar chiral ligands is realized by an efficient lithiation/electrophilic quench procedure, and the coordinating properties of one of them are highlighted together with its optical resolution.
ISSN:1477-9226
1477-9234
DOI:10.1039/b817192k