Static light scattering from microgel particles: model of variable dielectric permittivity

We perform static light scattering experiments on a dilute suspension of microgel particles and model the resultant form factors Pq by assuming an exponentially decaying dielectric permittivity. The result is that Pq is a Lorentzian function of the scattering wavevector q for length scales greater t...

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Veröffentlicht in:The Journal of chemical physics 2004-01, Vol.120 (1), p.374-378
Hauptverfasser: Fernández-Nieves, A, de las Nieves, F J, Fernández-Barbero, A
Format: Artikel
Sprache:eng
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Zusammenfassung:We perform static light scattering experiments on a dilute suspension of microgel particles and model the resultant form factors Pq by assuming an exponentially decaying dielectric permittivity. The result is that Pq is a Lorentzian function of the scattering wavevector q for length scales greater than the particle size; the width approximately corresponding to twice the particle radius. This simple model reasonably accounts for scattered light from both swollen and shrunken microgel phases.
ISSN:0021-9606
1089-7690
DOI:10.1063/1.1629281