The First Slipped Pseudo-Quadruple-Decker Complex of Phthalocyanines

The First Slipped Pseudo-Quadruple-Decker Complex of Phthalocyanines

The first slipped pseudo-quadruple-decker complex of phthalocyanines was formed unexpectedly upon treatment of the protonated double-decker SmIIIH(Pc)[Pc(α-OC4H9)8] with NaOH. The supramolecular structure contains two double-decker units linked by two sodium ions by an extremely rare coordination mo...

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Veröffentlicht in:Inorganic chemistry 2004-07, Vol.43 (15), p.4740-4742
Hauptverfasser: Zhang, Hongchuan, Wang, Rongmin, Zhu, Peihua, Lai, Zefeng, Han, Juan, Choi, Chi-Fung, Ng, Dennis K. P, Cui, Xuegui, Ma, Changqin, Jiang, Jianzhuang
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Sprache:eng
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Zusammenfassung:The first slipped pseudo-quadruple-decker complex of phthalocyanines was formed unexpectedly upon treatment of the protonated double-decker SmIIIH(Pc)[Pc(α-OC4H9)8] with NaOH. The supramolecular structure contains two double-decker units linked by two sodium ions by an extremely rare coordination mode of phthalocyanines in which an aza nitrogen atom and two oxygen atoms from neighboring alkoxy substituents form a tridentate ligand.
ISSN:0020-1669
1520-510X
DOI:10.1021/ic049705i