On the importance of steady-state isotopic techniques for the investigation of the mechanism of the reverse water-gas-shift reaction
The formation and reactivity of surface intermediates in the reverse water-gas-shift reaction on a Pt/CeO2 catalyst are critically dependent on the reaction conditions so that conclusions regarding the reaction mechanism cannot be inferred using ex operando conditions.
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2004-07 (14), p.1636-1637 |
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| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | The formation and reactivity of surface intermediates in the reverse water-gas-shift reaction on a Pt/CeO2 catalyst are critically dependent on the reaction conditions so that conclusions regarding the reaction mechanism cannot be inferred using ex operando conditions. |
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| ISSN: | 1359-7345 |
| DOI: | 10.1039/b403438d |