Reaction of gold(III) oxo complexes with alkenes. Synthesis of unprecedented gold alkene complexes, [Au(N,N)(alkene)][PF6]. Crystal structure of [Au(bipy(ip))(eta2-CH2=CHPh)][PF6] (bipy(ip) = 6-isopropyl-2,2'-bipyridine)

Reaction of gold(III) oxo complexes with alkenes. Synthesis of unprecedented gold alkene complexes, [Au(N,N)(alkene)][PF6]. Crystal structure of [Au(bipy(ip))(eta2-CH2=CHPh)][PF6] (bipy(ip) = 6-isopropyl-2,2'-bipyridine)

Gold alkene complexes [Au(bipyR)(eta2-alkene)][PF6] (bipyR = 6-alkyl-2,2'-bipyridine) have been obtained by reaction of gold(III) oxo complexes [Au2(bipyR)2(mu-O)2][PF6]2 with alkenes. The crystal structure of the styrene adduct [Au(bipy(ip))(eta2-CH2=CHPh)][PF6] (bipy(ip) = 6-isopropyl-2,2...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2004-07 (14), p.1618-1619
Hauptverfasser: Cinellu, Maria A, Minghetti, Giovanni, Stoccoro, Sergio, Zucca, Antonio, Manassero, Mario
Format: Artikel
Sprache:eng
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Zusammenfassung:Gold alkene complexes [Au(bipyR)(eta2-alkene)][PF6] (bipyR = 6-alkyl-2,2'-bipyridine) have been obtained by reaction of gold(III) oxo complexes [Au2(bipyR)2(mu-O)2][PF6]2 with alkenes. The crystal structure of the styrene adduct [Au(bipy(ip))(eta2-CH2=CHPh)][PF6] (bipy(ip) = 6-isopropyl-2,2'-bipyridine) has been solved by X-ray analysis.
ISSN:1359-7345
DOI:10.1039/b404890c