Kinetic Control over the Thermal Stability of the InH Bond: Synthesis and Characterization of Amido Indium Hydride Complexes

Kinetic Control over the Thermal Stability of the InH Bond: Synthesis and Characterization of Amido Indium Hydride Complexes

High thermal stability is a characteristic feature of the depicted amido indium hydride complex (In red; hydride yellow), which is amongst the first to be synthesized and characterized. The stability arises from steric shielding of the InH bond, which frustrates the formation of the intermolecular...

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Veröffentlicht in:Angewandte Chemie International Edition 2004-07, Vol.43 (29), p.3852-3855
Hauptverfasser: Baker, Robert J., Jones, Cameron, Junk, Peter C., Kloth, Marc
Format: Artikel
Sprache:eng
Schlagworte:
amides
gallium
hydrides
indium
structure elucidation
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Zusammenfassung:High thermal stability is a characteristic feature of the depicted amido indium hydride complex (In red; hydride yellow), which is amongst the first to be synthesized and characterized. The stability arises from steric shielding of the InH bond, which frustrates the formation of the intermolecular InHIn bridges.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200460304