Efficient Acyclic Stereocontrol Using the Tethered Aminohydroxylation Reaction

Efficient Acyclic Stereocontrol Using the Tethered Aminohydroxylation Reaction

The tethered aminohydroxylation (TA) of acyclic allylic carbamates has been achieved in a stereospecific and stereoselective manner. Unusually high levels of stereocontrol were observed in the oxidation of 1,1-disubstituted substrates.

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Veröffentlicht in:Organic letters 2004-07, Vol.6 (15), p.2583-2585
Hauptverfasser: Donohoe, Timothy J, Johnson, Peter D, Pye, Richard J, Keenan, Martine
Format: Artikel
Sprache:eng
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Zusammenfassung:The tethered aminohydroxylation (TA) of acyclic allylic carbamates has been achieved in a stereospecific and stereoselective manner. Unusually high levels of stereocontrol were observed in the oxidation of 1,1-disubstituted substrates.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol049136i