Simple Synthesis of an Allenylidene Heptavalent Rhenium(d 0) Complex

This paper reports a simple way to synthesize an allenylidene rhenium(VII) complex. The diimido adamantyl-thiolato allenylidene rhenium(VII) complex 2 was obtained through a metathetical reaction of phosphonioalkylidyne rhenium complex 1 with diphenylketene and also structurally analyzed with X-ray...

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Veröffentlicht in:	Journal of the American Chemical Society 2004-07, Vol.126 (28), p.8660-8661
Hauptverfasser:	Li, Xiaoyan, Schopf, Markus, Stephan, Jürgen, Kippe, Jennifer, Harms, Klaus, Sundermeyer, Jörg
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Condensed matter: structure, mechanical and thermal properties Coordination compounds Exact sciences and technology Inorganic chemistry and origins of life Inorganic compounds Metal complexes Physics Preparations and properties Structure of solids and liquids crystallography Structure of specific crystalline solids
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Beschreibung
Zusammenfassung:	This paper reports a simple way to synthesize an allenylidene rhenium(VII) complex. The diimido adamantyl-thiolato allenylidene rhenium(VII) complex 2 was obtained through a metathetical reaction of phosphonioalkylidyne rhenium complex 1 with diphenylketene and also structurally analyzed with X-ray diffraction. Complex 2 is the first d 0 allenylidene complex with structure information.
ISSN:	0002-7863 1520-5126
DOI:	10.1021/ja048030f