The first example of a Si-bridged tris(pyridyl) ligand; synthesis and structure of [MeSi(2-C5H4N)3LiX](X = 0.2Br, 0.8Cl)

The first example of a Si-bridged tris(pyridyl) ligand; synthesis and structure of [MeSi(2-C5H4N)3LiX](X = 0.2Br, 0.8Cl)

The low-temperature reaction of MeSiCl3 with 2-Li-C5H4N (1:3 equivalents) in thf gives [MeSi(2-C5H4N)3LiX](X = 0.2Br, 0.8Cl), containing the first example of a Si-bridged tris(pyridyl) ligand.

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2004-02 (3), p.361-362
Hauptverfasser: García, Felipe, Hopkins, Alexander D, Humphrey, Simon M, McPartlin, Mary, Rogers, Michael C, Wright, Dominic S
Format: Artikel
Sprache:eng
Schlagworte:
Heterocyclic Compounds, Bridged-Ring - chemical synthesis
Heterocyclic Compounds, Bridged-Ring - chemistry
Ligands
Models, Molecular
Molecular Conformation
Organometallic Compounds - chemical synthesis
Organometallic Compounds - chemistry
Organosilicon Compounds - chemical synthesis
Organosilicon Compounds - chemistry
Pyridines - chemistry
Temperature
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Zusammenfassung:The low-temperature reaction of MeSiCl3 with 2-Li-C5H4N (1:3 equivalents) in thf gives [MeSi(2-C5H4N)3LiX](X = 0.2Br, 0.8Cl), containing the first example of a Si-bridged tris(pyridyl) ligand.
ISSN:1477-9226
1477-9234
DOI:10.1039/b315503j