Construction of Highly Oriented Crystalline Surface Coordination Polymers Composed of Copper Dithiooxamide Complexes

Construction of Highly Oriented Crystalline Surface Coordination Polymers Composed of Copper Dithiooxamide Complexes

Layer-by-layer bottom-up crystal engineering of metal−organic crystals at the surface of sapphire or glass from organic (rubeanic acid and derivatives) and inorganic (Cu2+) components which when mixed in solution form instantly an amorphous solid with high proton conduction.

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Veröffentlicht in:Journal of the American Chemical Society 2008-11, Vol.130 (47), p.15778-15779
Hauptverfasser: Kanaizuka, Katsuhiko, Haruki, Rie, Sakata, Osami, Yoshimoto, Mamoru, Akita, Yasuyuki, Kitagawa, Hiroshi
Format: Artikel
Sprache:eng
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Beschreibung
Zusammenfassung:Layer-by-layer bottom-up crystal engineering of metal−organic crystals at the surface of sapphire or glass from organic (rubeanic acid and derivatives) and inorganic (Cu2+) components which when mixed in solution form instantly an amorphous solid with high proton conduction.
ISSN:0002-7863
1520-5126
DOI:10.1021/ja806799t