Ultra-Low Shrinkage Hybrid Photosensitive Material for Two-Photon Polymerization Microfabrication
Investigations into the structuring by two-photon polymerization of a nonshrinking, photosensitive, zirconium sol−gel material are presented. This hybrid material can be photostructured even when it contains up to 30 mol % of zirconium propoxide (ZPO); by varying the material’s inorganic content, it...
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| Veröffentlicht in: | ACS nano 2008-11, Vol.2 (11), p.2257-2262 |
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| creator | Ovsianikov, Aleksandr Viertl, Jacques Chichkov, Boris Oubaha, Mohamed MacCraith, Brian Sakellari, Ioanna Giakoumaki, Anastasia Gray, David Vamvakaki, Maria Farsari, Maria Fotakis, Costas |
| description | Investigations into the structuring by two-photon polymerization of a nonshrinking, photosensitive, zirconium sol−gel material are presented. This hybrid material can be photostructured even when it contains up to 30 mol % of zirconium propoxide (ZPO); by varying the material’s inorganic content, it is possible to modify and tune its refractive index. The introduction of ZPO significantly increases the photosensitivity of the resulting photopolymer. The fabricated three-dimensional photonic crystal structures demonstrate high resolution and a clear band-stop in the near-IR region. In contrast to common practice, no additional effort is required to precompensate for shrinkage or to improve the structural stability of the fabricated photonic crystals; this, combined with the possibility of tuning this material’s optical, mechanical, and chemical properties, makes it suitable for a variety of applications by two-photon polymerization manufacturing. |
| doi_str_mv | 10.1021/nn800451w |
| format | Article |
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This hybrid material can be photostructured even when it contains up to 30 mol % of zirconium propoxide (ZPO); by varying the material’s inorganic content, it is possible to modify and tune its refractive index. The introduction of ZPO significantly increases the photosensitivity of the resulting photopolymer. The fabricated three-dimensional photonic crystal structures demonstrate high resolution and a clear band-stop in the near-IR region. In contrast to common practice, no additional effort is required to precompensate for shrinkage or to improve the structural stability of the fabricated photonic crystals; this, combined with the possibility of tuning this material’s optical, mechanical, and chemical properties, makes it suitable for a variety of applications by two-photon polymerization manufacturing.</description><identifier>ISSN: 1936-0851</identifier><identifier>EISSN: 1936-086X</identifier><identifier>DOI: 10.1021/nn800451w</identifier><identifier>PMID: 19206391</identifier><language>eng</language><publisher>United States: American Chemical Society</publisher><subject>Chemistry, Inorganic - methods ; Crystallization ; Equipment Design ; Infrared Rays ; Materials Testing ; Models, Chemical ; Molecular Conformation ; Oxides - chemistry ; Phase Transition ; Photochemistry - methods ; Photons ; Refractometry ; Spectroscopy, Fourier Transform Infrared ; Spectroscopy, Near-Infrared ; Zirconium - chemistry</subject><ispartof>ACS nano, 2008-11, Vol.2 (11), p.2257-2262</ispartof><rights>Copyright © 2008 American Chemical Society</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a313t-b998090660cc89f694439449d99f5d81c5c211421a0a94b08041dfcd0cf53ba13</citedby><cites>FETCH-LOGICAL-a313t-b998090660cc89f694439449d99f5d81c5c211421a0a94b08041dfcd0cf53ba13</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/nn800451w$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/nn800451w$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,777,781,2752,27057,27905,27906,56719,56769</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/19206391$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Ovsianikov, Aleksandr</creatorcontrib><creatorcontrib>Viertl, Jacques</creatorcontrib><creatorcontrib>Chichkov, Boris</creatorcontrib><creatorcontrib>Oubaha, Mohamed</creatorcontrib><creatorcontrib>MacCraith, Brian</creatorcontrib><creatorcontrib>Sakellari, Ioanna</creatorcontrib><creatorcontrib>Giakoumaki, Anastasia</creatorcontrib><creatorcontrib>Gray, David</creatorcontrib><creatorcontrib>Vamvakaki, Maria</creatorcontrib><creatorcontrib>Farsari, Maria</creatorcontrib><creatorcontrib>Fotakis, Costas</creatorcontrib><title>Ultra-Low Shrinkage Hybrid Photosensitive Material for Two-Photon Polymerization Microfabrication</title><title>ACS nano</title><addtitle>ACS Nano</addtitle><description>Investigations into the structuring by two-photon polymerization of a nonshrinking, photosensitive, zirconium sol−gel material are presented. This hybrid material can be photostructured even when it contains up to 30 mol % of zirconium propoxide (ZPO); by varying the material’s inorganic content, it is possible to modify and tune its refractive index. The introduction of ZPO significantly increases the photosensitivity of the resulting photopolymer. The fabricated three-dimensional photonic crystal structures demonstrate high resolution and a clear band-stop in the near-IR region. In contrast to common practice, no additional effort is required to precompensate for shrinkage or to improve the structural stability of the fabricated photonic crystals; this, combined with the possibility of tuning this material’s optical, mechanical, and chemical properties, makes it suitable for a variety of applications by two-photon polymerization manufacturing.</description><subject>Chemistry, Inorganic - methods</subject><subject>Crystallization</subject><subject>Equipment Design</subject><subject>Infrared Rays</subject><subject>Materials Testing</subject><subject>Models, Chemical</subject><subject>Molecular Conformation</subject><subject>Oxides - chemistry</subject><subject>Phase Transition</subject><subject>Photochemistry - methods</subject><subject>Photons</subject><subject>Refractometry</subject><subject>Spectroscopy, Fourier Transform Infrared</subject><subject>Spectroscopy, Near-Infrared</subject><subject>Zirconium - chemistry</subject><issn>1936-0851</issn><issn>1936-086X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNptkE1LAzEQhoMoVqsH_4DsRcHD6sx-pMlRilqhxYIteFuy2axN3W5qsmupv97YlnrxMMzXw8vMS8gFwi1ChHd1zQCSFFcH5AR5TENg9O1wX6fYIafOzQHSHuvRY9JBHgGNOZ4QMa0aK8KhWQWvM6vrD_GugsE6t7oIxjPTGKdqpxv9pYKRaJTVogpKY4PJyoSbfR2MTbVe-M23aLRvR1paUwqvIDeDM3JUisqp813ukunjw6Q_CIcvT8_9-2EoYoybMOecAQdKQUrGS8qTJPbBC87LtGAoUxkhJhEKEDzJgUGCRSkLkGUa5wLjLrne6i6t-WyVa7KFdlJVlaiVaV1GKWWYsJ4Hb7agv9M5q8psafVC2HWGkP36me399OzlTrTNF6r4I3cGeuBqCwjpsrlpbe1__EfoBxvifVE</recordid><startdate>20081125</startdate><enddate>20081125</enddate><creator>Ovsianikov, Aleksandr</creator><creator>Viertl, Jacques</creator><creator>Chichkov, Boris</creator><creator>Oubaha, Mohamed</creator><creator>MacCraith, Brian</creator><creator>Sakellari, Ioanna</creator><creator>Giakoumaki, Anastasia</creator><creator>Gray, David</creator><creator>Vamvakaki, Maria</creator><creator>Farsari, Maria</creator><creator>Fotakis, Costas</creator><general>American Chemical Society</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20081125</creationdate><title>Ultra-Low Shrinkage Hybrid Photosensitive Material for Two-Photon Polymerization Microfabrication</title><author>Ovsianikov, Aleksandr ; Viertl, Jacques ; Chichkov, Boris ; Oubaha, Mohamed ; MacCraith, Brian ; Sakellari, Ioanna ; Giakoumaki, Anastasia ; Gray, David ; Vamvakaki, Maria ; Farsari, Maria ; Fotakis, Costas</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a313t-b998090660cc89f694439449d99f5d81c5c211421a0a94b08041dfcd0cf53ba13</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2008</creationdate><topic>Chemistry, Inorganic - methods</topic><topic>Crystallization</topic><topic>Equipment Design</topic><topic>Infrared Rays</topic><topic>Materials Testing</topic><topic>Models, Chemical</topic><topic>Molecular Conformation</topic><topic>Oxides - chemistry</topic><topic>Phase Transition</topic><topic>Photochemistry - methods</topic><topic>Photons</topic><topic>Refractometry</topic><topic>Spectroscopy, Fourier Transform Infrared</topic><topic>Spectroscopy, Near-Infrared</topic><topic>Zirconium - chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ovsianikov, Aleksandr</creatorcontrib><creatorcontrib>Viertl, Jacques</creatorcontrib><creatorcontrib>Chichkov, Boris</creatorcontrib><creatorcontrib>Oubaha, Mohamed</creatorcontrib><creatorcontrib>MacCraith, Brian</creatorcontrib><creatorcontrib>Sakellari, Ioanna</creatorcontrib><creatorcontrib>Giakoumaki, Anastasia</creatorcontrib><creatorcontrib>Gray, David</creatorcontrib><creatorcontrib>Vamvakaki, Maria</creatorcontrib><creatorcontrib>Farsari, Maria</creatorcontrib><creatorcontrib>Fotakis, Costas</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>ACS nano</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ovsianikov, Aleksandr</au><au>Viertl, Jacques</au><au>Chichkov, Boris</au><au>Oubaha, Mohamed</au><au>MacCraith, Brian</au><au>Sakellari, Ioanna</au><au>Giakoumaki, Anastasia</au><au>Gray, David</au><au>Vamvakaki, Maria</au><au>Farsari, Maria</au><au>Fotakis, Costas</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Ultra-Low Shrinkage Hybrid Photosensitive Material for Two-Photon Polymerization Microfabrication</atitle><jtitle>ACS nano</jtitle><addtitle>ACS Nano</addtitle><date>2008-11-25</date><risdate>2008</risdate><volume>2</volume><issue>11</issue><spage>2257</spage><epage>2262</epage><pages>2257-2262</pages><issn>1936-0851</issn><eissn>1936-086X</eissn><abstract>Investigations into the structuring by two-photon polymerization of a nonshrinking, photosensitive, zirconium sol−gel material are presented. This hybrid material can be photostructured even when it contains up to 30 mol % of zirconium propoxide (ZPO); by varying the material’s inorganic content, it is possible to modify and tune its refractive index. The introduction of ZPO significantly increases the photosensitivity of the resulting photopolymer. The fabricated three-dimensional photonic crystal structures demonstrate high resolution and a clear band-stop in the near-IR region. In contrast to common practice, no additional effort is required to precompensate for shrinkage or to improve the structural stability of the fabricated photonic crystals; this, combined with the possibility of tuning this material’s optical, mechanical, and chemical properties, makes it suitable for a variety of applications by two-photon polymerization manufacturing.</abstract><cop>United States</cop><pub>American Chemical Society</pub><pmid>19206391</pmid><doi>10.1021/nn800451w</doi><tpages>6</tpages></addata></record> |
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| subjects | Chemistry, Inorganic - methods Crystallization Equipment Design Infrared Rays Materials Testing Models, Chemical Molecular Conformation Oxides - chemistry Phase Transition Photochemistry - methods Photons Refractometry Spectroscopy, Fourier Transform Infrared Spectroscopy, Near-Infrared Zirconium - chemistry |
| title | Ultra-Low Shrinkage Hybrid Photosensitive Material for Two-Photon Polymerization Microfabrication |
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