Metric engineering of perfluorocarbon-hydrocarbon layered solids driven by the halogen bonding

The halogen bonding driven self-assembly of 1,4-dicyanobutane and 1,6-dicyanohexane with a range of perfluorinated telechelic diiodoalkanes yields layered 1D, infinite chain co-crystals. The structure and metrics of these co-crystals are remarkably predictable.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2004-07 (13), p.1492-1493
Hauptverfasser: Metrangolo, Pierangelo, Pilati, Tullio, Resnati, Giuseppe, Stevenazzi, Andrea
Format: Artikel
Sprache:eng
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Zusammenfassung:The halogen bonding driven self-assembly of 1,4-dicyanobutane and 1,6-dicyanohexane with a range of perfluorinated telechelic diiodoalkanes yields layered 1D, infinite chain co-crystals. The structure and metrics of these co-crystals are remarkably predictable.
ISSN:1359-7345
1364-548X
DOI:10.1039/b402305f