Low temperature NO disproportionation by Mn porphyrin. Spectroscopic characterization of the unstable nitrosyl nitrito complex MnIII(TPP)(NO)(ONO)

Low temperature NO disproportionation by Mn porphyrin. Spectroscopic characterization of the unstable nitrosyl nitrito complex MnIII(TPP)(NO)(ONO)

Reaction of NO gas with sublimed layers of the Mn(II)TPP (TPP =meso-tetraphenylporphyrinato2-) at low temperature leads to nitric oxide disproportionation. UV-Vis and FTIR spectroscopy with isotopically substituted nitrogen oxides revealed formation of the unstable species identified as trans-Mn(III...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2004-07 (13), p.1488-1489
Hauptverfasser: Martirosyan, Garik G, Azizyan, Arsen S, Kurtikyan, Tigran S, Ford, Peter C
Format: Artikel
Sprache:eng
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Zusammenfassung:Reaction of NO gas with sublimed layers of the Mn(II)TPP (TPP =meso-tetraphenylporphyrinato2-) at low temperature leads to nitric oxide disproportionation. UV-Vis and FTIR spectroscopy with isotopically substituted nitrogen oxides revealed formation of the unstable species identified as trans-Mn(III)(TPP)(NO)(ONO).
ISSN:1359-7345
1364-548X
DOI:10.1039/b404491f