Oriented UHMW-PE/CNT composite tapes by a solution casting-drawing process using mixed-solvents

Ultra-high molecular weight polyethylene/multi-wall carbon nanotube (UHMW-PE/MWNT) composites have been prepared by a novel approach which involves the use of a mixture of solvents during the gelation process. By combining one of the best known organic solvents for nanotubes, N, N-dimethylformamide...

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Veröffentlicht in:European polymer journal 2009-10, Vol.45 (10), p.2741-2748
Hauptverfasser: Ciselli, Paola, Zhang, Rui, Wang, Zhujuan, Reynolds, Christopher T., Baxendale, Mark, Peijs, Ton
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Sprache:eng
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Zusammenfassung:Ultra-high molecular weight polyethylene/multi-wall carbon nanotube (UHMW-PE/MWNT) composites have been prepared by a novel approach which involves the use of a mixture of solvents during the gelation process. By combining one of the best known organic solvents for nanotubes, N, N-dimethylformamide (DMF) with xylene and use this mixed-solvent in the gelation/crystallisation process for UHMW-PE/MWNT composite fabrication, an attempt is made to improve the dispersion of carbon nanotubes in UHMW-PE. The obtained films were drawn to obtain highly oriented tapes, which were characterized in terms of electrical and mechanical properties. The conductivity of the drawn tapes is maintained at 10 −4 S/m at draw ratio 30, two orders of magnitude higher than the minimum level required to provide electrostatic discharge. Although the mechanical properties are compromised by use of DMF and MWNTs, the Young’s modulus still remains at 25 GPa, in comparison with 35 GPa for pure UHMW-PE tape at draw ratio 30. SEM image of solid-state drawn ( λ = 30) UHMW-PE tape containing MWNTs, showing highly oriented nanotubes.
ISSN:0014-3057
1873-1945
DOI:10.1016/j.eurpolymj.2009.06.004