Eco‐Friendly Olefin Dihydroxylation Catalyzed by Diphenyl Diselenide

Eco‐Friendly Olefin Dihydroxylation Catalyzed by Diphenyl Diselenide

The first general and efficient diphenyl diselenide‐catalyzed dihydroxylation of double bonds is presented. Hydrogen peroxide can be used as the oxidizing agent, affording generally good yields and high diasteroselectivity.

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Veröffentlicht in:Advanced synthesis & catalysis 2008-12, Vol.350 (18), p.2881-2884
Hauptverfasser: Santoro, Stefano, Santi, Claudio, Sabatini, Michela, Testaferri, Lorenzo, Tiecco, Marcello
Format: Artikel
Sprache:eng
Schlagworte:
alkenes
catalysis
hydrogen peroxide
hydroxylation
selenium
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Beschreibung
Zusammenfassung:The first general and efficient diphenyl diselenide‐catalyzed dihydroxylation of double bonds is presented. Hydrogen peroxide can be used as the oxidizing agent, affording generally good yields and high diasteroselectivity.
ISSN:1615-4150
1615-4169
DOI:10.1002/adsc.200800571