Cherry stones as precursor of activated carbons for supercapacitors

It is shown that cherry stones-wastes can be recycled as activated carbons for electrode material in supercapacitors. KOH-activation of this precursor at 800–900 °C is an efficient process to obtain carbons with large specific surface areas (1100–1300 m 2 g −1), average pore sizes around 0.9–1.3 nm,...

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Veröffentlicht in:Materials chemistry and physics 2009-03, Vol.114 (1), p.323-327
Hauptverfasser: Olivares-Marín, M., Fernández, J.A., Lázaro, M.J., Fernández-González, C., Macías-García, A., Gómez-Serrano, V., Stoeckli, F., Centeno, T.A.
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Sprache:eng
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Zusammenfassung:It is shown that cherry stones-wastes can be recycled as activated carbons for electrode material in supercapacitors. KOH-activation of this precursor at 800–900 °C is an efficient process to obtain carbons with large specific surface areas (1100–1300 m 2 g −1), average pore sizes around 0.9–1.3 nm, which makes them accessible to electrolyte ions, and conductivities between 1 and 2 S cm −1. These features lead to capacitances at low current density as high as 230 F g −1 in 2 M H 2SO 4 aqueous electrolyte and 120 F g −1 in the aprotic medium 1 M (C 2H 5) 4NBF 4/acetonitrile. Furthermore, high performance is also achieved at high current densities, which means that this type of materials competes well with commercial carbons used at present in supercapacitors.
ISSN:0254-0584
1879-3312
DOI:10.1016/j.matchemphys.2008.09.010