Fluorescent Gold Nanoparticle Superlattices

3D superlattices of fluorescent gold nanoparticles are prepared at an air/water interface. The hexagonal assembly extends over several micrometers, and crystals of triangular morphology are imaged using the fluorescence emission of the monolayers protecting the nanoparticles (see figure). Surprising...

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Veröffentlicht in:Advanced materials (Weinheim) 2008-12, Vol.20 (24), p.4719-4723
Hauptverfasser: Nishida, Naoki, Shibu, Edakkattuparambil S., Yao, Hiroshi, Oonishi, Tsugao, Kimura, Keisaku, Pradeep, Thalappil
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Sprache:eng
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Zusammenfassung:3D superlattices of fluorescent gold nanoparticles are prepared at an air/water interface. The hexagonal assembly extends over several micrometers, and crystals of triangular morphology are imaged using the fluorescence emission of the monolayers protecting the nanoparticles (see figure). Surprisingly, the superlattices are fluorescent even though the fluorescein derivative is close to the metallic core and strong quenching is expected.
ISSN:0935-9648
1521-4095
DOI:10.1002/adma.200800632