Low-temperature heat capacity of sodium erbium molybdophosphate Na2Er(MoO4)(PO4)
Adiabatic calorimetry is used to measure the low-temperature heat capacity of Na2Er(MoO4)(PO4)from 6.41 to 347.87 K. Experimental data are used to calculate the thermodynamic functions of Na2Er(MoO4)(PO4), which at 298.15 K are as follows: C p (298.15 K) = 243,3 - 0.4 J/(K mol), S (298.15 K) = 312.8...
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Veröffentlicht in: | Russian journal of inorganic chemistry 2007-10, Vol.52 (10), p.1607-1611 |
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Hauptverfasser: | , , , , , , , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | Adiabatic calorimetry is used to measure the low-temperature heat capacity of Na2Er(MoO4)(PO4)from 6.41 to 347.87 K. Experimental data are used to calculate the thermodynamic functions of Na2Er(MoO4)(PO4), which at 298.15 K are as follows: C p (298.15 K) = 243,3 - 0.4 J/(K mol), S (298.15 K) = 312.8 - 0.8 J/(K mol), H (298.15 K) - H (0 K) = 45280 - 90 J/mol, and Q(298.15 K) = 136.1 - 0.3 J/(K mol). A diffuse heat-capacity anomaly associated with splitting of the Stark levels (Schottky anomaly) is discovered in the low-temperature region. |
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ISSN: | 0036-0236 1531-8613 |
DOI: | 10.1134/S0036023607100221 |