Low-temperature heat capacity of sodium erbium molybdophosphate Na2Er(MoO4)(PO4)

Adiabatic calorimetry is used to measure the low-temperature heat capacity of Na2Er(MoO4)(PO4)from 6.41 to 347.87 K. Experimental data are used to calculate the thermodynamic functions of Na2Er(MoO4)(PO4), which at 298.15 K are as follows: C p (298.15 K) = 243,3 - 0.4 J/(K mol), S (298.15 K) = 312.8...

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Veröffentlicht in:Russian journal of inorganic chemistry 2007-10, Vol.52 (10), p.1607-1611
Hauptverfasser: Gavrichev, K. S., Smirnova, N. N., Ryumin, M. A., Gurevich, V. M., Tyurin, A. V., Komissarova, L. N., Spiridonov, F. M., Danilov, V. P.
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Sprache:eng
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Zusammenfassung:Adiabatic calorimetry is used to measure the low-temperature heat capacity of Na2Er(MoO4)(PO4)from 6.41 to 347.87 K. Experimental data are used to calculate the thermodynamic functions of Na2Er(MoO4)(PO4), which at 298.15 K are as follows: C p (298.15 K) = 243,3 - 0.4 J/(K mol), S (298.15 K) = 312.8 - 0.8 J/(K mol), H (298.15 K) - H (0 K) = 45280 - 90 J/mol, and Q(298.15 K) = 136.1 - 0.3 J/(K mol). A diffuse heat-capacity anomaly associated with splitting of the Stark levels (Schottky anomaly) is discovered in the low-temperature region.
ISSN:0036-0236
1531-8613
DOI:10.1134/S0036023607100221