From Reactive Intermediates to Stable Compounds

Scheschkewitz et al report the synthesis of a diradical that is stable indefinitely at room temperature. The work may open the door to new types of molecular magnetism and conductivity. The first stable carbon-based diradical, Schlenk's hydrocarbon, was prepared in 1915.

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Veröffentlicht in:Science (American Association for the Advancement of Science) 2002-03, Vol.295 (5561), p.1846-1847
1. Verfasser: Wentrup, Curt
Format: Artikel
Sprache:eng
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Zusammenfassung:Scheschkewitz et al report the synthesis of a diradical that is stable indefinitely at room temperature. The work may open the door to new types of molecular magnetism and conductivity. The first stable carbon-based diradical, Schlenk's hydrocarbon, was prepared in 1915.
ISSN:0036-8075
1095-9203
DOI:10.1126/science.1070364