Spinel Li4Ti5O12 as a reversible anode material down to 0 V
The electrochemical behavior of Li1.33Ti1.67O4 was investigated as an anode material discharged to 0 V using X-ray diffraction (XRD), galvanostatic cell cycling and ac impedance spectroscopy. The XRD results indicate that the lattice framework of Li1.33Ti1.67O4 is almost unchanged even after it is d...
Gespeichert in:
| Veröffentlicht in: | Journal of alloys and compounds 2008-10, Vol.465 (1-2), p.375-379 |
|---|---|
| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 379 |
|---|---|
| container_issue | 1-2 |
| container_start_page | 375 |
| container_title | Journal of alloys and compounds |
| container_volume | 465 |
| creator | YAO, X. L XIE, S NIAN, H. Q CHEN, C. H |
| description | The electrochemical behavior of Li1.33Ti1.67O4 was investigated as an anode material discharged to 0 V using X-ray diffraction (XRD), galvanostatic cell cycling and ac impedance spectroscopy. The XRD results indicate that the lattice framework of Li1.33Ti1.67O4 is almost unchanged even after it is discharged to 0 V. The Li1.33Ti1.67O4 electrode can be cycled in the voltage range between 0 and 3.0 V with excellent cyclability and a capacity of about 200 mAh/g. During the discharge process, a 0.75 V plateau is also observed in addition to the usual 1.5 V plateau. The capacity associated with the 0.75 V plateau varies with current density and temperature. The possible cause of this low potential plateau is discussed and attributed to a carbon-triggered-capacity (CTC) effect. |
| doi_str_mv | 10.1016/j.jallcom.2007.10.113 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_pasca</sourceid><recordid>TN_cdi_proquest_miscellaneous_35179767</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>35179767</sourcerecordid><originalsourceid>FETCH-LOGICAL-p216t-e33c587599365be6f4d56b04e16072f76a8ac8b417c7acac19352b01f5cab3893</originalsourceid><addsrcrecordid>eNotjktLAzEURoMoWKs_QchGdzPeJJMXrqT4goEurG6HO2kGUjIPk6niv7diVwc-Dh-HkGsGJQOm7nblDmN0Y19yAF3-zUyckAUzWhSVUvaULMByWRhhzDm5yHkHAMwKtiD3b1MYfKR1qDZBrhmnmCnS5L98yqGNnuIwbj3tcfYpYKTb8Xug80iBflySsw5j9ldHLsn70-Nm9VLU6-fX1UNdTJypufBCOGm0tFYo2XrVVVupWqg8U6B5pxUadKatmHYaHbpDmOQtsE46bIWxYklu_3-nNH7ufZ6bPmTnY8TBj_vcCMm01UofxJujiNlh7BIOLuRmSqHH9NNwUFZrqMQv9eNX8g</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>35179767</pqid></control><display><type>article</type><title>Spinel Li4Ti5O12 as a reversible anode material down to 0 V</title><source>Access via ScienceDirect (Elsevier)</source><creator>YAO, X. L ; XIE, S ; NIAN, H. Q ; CHEN, C. H</creator><creatorcontrib>YAO, X. L ; XIE, S ; NIAN, H. Q ; CHEN, C. H</creatorcontrib><description>The electrochemical behavior of Li1.33Ti1.67O4 was investigated as an anode material discharged to 0 V using X-ray diffraction (XRD), galvanostatic cell cycling and ac impedance spectroscopy. The XRD results indicate that the lattice framework of Li1.33Ti1.67O4 is almost unchanged even after it is discharged to 0 V. The Li1.33Ti1.67O4 electrode can be cycled in the voltage range between 0 and 3.0 V with excellent cyclability and a capacity of about 200 mAh/g. During the discharge process, a 0.75 V plateau is also observed in addition to the usual 1.5 V plateau. The capacity associated with the 0.75 V plateau varies with current density and temperature. The possible cause of this low potential plateau is discussed and attributed to a carbon-triggered-capacity (CTC) effect.</description><identifier>ISSN: 0925-8388</identifier><identifier>EISSN: 1873-4669</identifier><identifier>DOI: 10.1016/j.jallcom.2007.10.113</identifier><language>eng</language><publisher>Lausanne: Elsevier</publisher><subject>Chemistry ; Electrochemistry ; Electrodes: preparations and properties ; Exact sciences and technology ; General and physical chemistry</subject><ispartof>Journal of alloys and compounds, 2008-10, Vol.465 (1-2), p.375-379</ispartof><rights>2008 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>315,782,786,27931,27932</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=20697704$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>YAO, X. L</creatorcontrib><creatorcontrib>XIE, S</creatorcontrib><creatorcontrib>NIAN, H. Q</creatorcontrib><creatorcontrib>CHEN, C. H</creatorcontrib><title>Spinel Li4Ti5O12 as a reversible anode material down to 0 V</title><title>Journal of alloys and compounds</title><description>The electrochemical behavior of Li1.33Ti1.67O4 was investigated as an anode material discharged to 0 V using X-ray diffraction (XRD), galvanostatic cell cycling and ac impedance spectroscopy. The XRD results indicate that the lattice framework of Li1.33Ti1.67O4 is almost unchanged even after it is discharged to 0 V. The Li1.33Ti1.67O4 electrode can be cycled in the voltage range between 0 and 3.0 V with excellent cyclability and a capacity of about 200 mAh/g. During the discharge process, a 0.75 V plateau is also observed in addition to the usual 1.5 V plateau. The capacity associated with the 0.75 V plateau varies with current density and temperature. The possible cause of this low potential plateau is discussed and attributed to a carbon-triggered-capacity (CTC) effect.</description><subject>Chemistry</subject><subject>Electrochemistry</subject><subject>Electrodes: preparations and properties</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><issn>0925-8388</issn><issn>1873-4669</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><recordid>eNotjktLAzEURoMoWKs_QchGdzPeJJMXrqT4goEurG6HO2kGUjIPk6niv7diVwc-Dh-HkGsGJQOm7nblDmN0Y19yAF3-zUyckAUzWhSVUvaULMByWRhhzDm5yHkHAMwKtiD3b1MYfKR1qDZBrhmnmCnS5L98yqGNnuIwbj3tcfYpYKTb8Xug80iBflySsw5j9ldHLsn70-Nm9VLU6-fX1UNdTJypufBCOGm0tFYo2XrVVVupWqg8U6B5pxUadKatmHYaHbpDmOQtsE46bIWxYklu_3-nNH7ufZ6bPmTnY8TBj_vcCMm01UofxJujiNlh7BIOLuRmSqHH9NNwUFZrqMQv9eNX8g</recordid><startdate>20081006</startdate><enddate>20081006</enddate><creator>YAO, X. L</creator><creator>XIE, S</creator><creator>NIAN, H. Q</creator><creator>CHEN, C. H</creator><general>Elsevier</general><scope>IQODW</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20081006</creationdate><title>Spinel Li4Ti5O12 as a reversible anode material down to 0 V</title><author>YAO, X. L ; XIE, S ; NIAN, H. Q ; CHEN, C. H</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-p216t-e33c587599365be6f4d56b04e16072f76a8ac8b417c7acac19352b01f5cab3893</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2008</creationdate><topic>Chemistry</topic><topic>Electrochemistry</topic><topic>Electrodes: preparations and properties</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>YAO, X. L</creatorcontrib><creatorcontrib>XIE, S</creatorcontrib><creatorcontrib>NIAN, H. Q</creatorcontrib><creatorcontrib>CHEN, C. H</creatorcontrib><collection>Pascal-Francis</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of alloys and compounds</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>YAO, X. L</au><au>XIE, S</au><au>NIAN, H. Q</au><au>CHEN, C. H</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Spinel Li4Ti5O12 as a reversible anode material down to 0 V</atitle><jtitle>Journal of alloys and compounds</jtitle><date>2008-10-06</date><risdate>2008</risdate><volume>465</volume><issue>1-2</issue><spage>375</spage><epage>379</epage><pages>375-379</pages><issn>0925-8388</issn><eissn>1873-4669</eissn><abstract>The electrochemical behavior of Li1.33Ti1.67O4 was investigated as an anode material discharged to 0 V using X-ray diffraction (XRD), galvanostatic cell cycling and ac impedance spectroscopy. The XRD results indicate that the lattice framework of Li1.33Ti1.67O4 is almost unchanged even after it is discharged to 0 V. The Li1.33Ti1.67O4 electrode can be cycled in the voltage range between 0 and 3.0 V with excellent cyclability and a capacity of about 200 mAh/g. During the discharge process, a 0.75 V plateau is also observed in addition to the usual 1.5 V plateau. The capacity associated with the 0.75 V plateau varies with current density and temperature. The possible cause of this low potential plateau is discussed and attributed to a carbon-triggered-capacity (CTC) effect.</abstract><cop>Lausanne</cop><pub>Elsevier</pub><doi>10.1016/j.jallcom.2007.10.113</doi><tpages>5</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0925-8388 |
| ispartof | Journal of alloys and compounds, 2008-10, Vol.465 (1-2), p.375-379 |
| issn | 0925-8388 1873-4669 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_35179767 |
| source | Access via ScienceDirect (Elsevier) |
| subjects | Chemistry Electrochemistry Electrodes: preparations and properties Exact sciences and technology General and physical chemistry |
| title | Spinel Li4Ti5O12 as a reversible anode material down to 0 V |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-05T04%3A55%3A55IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_pasca&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Spinel%20Li4Ti5O12%20as%20a%20reversible%20anode%20material%20down%20to%200%20V&rft.jtitle=Journal%20of%20alloys%20and%20compounds&rft.au=YAO,%20X.%20L&rft.date=2008-10-06&rft.volume=465&rft.issue=1-2&rft.spage=375&rft.epage=379&rft.pages=375-379&rft.issn=0925-8388&rft.eissn=1873-4669&rft_id=info:doi/10.1016/j.jallcom.2007.10.113&rft_dat=%3Cproquest_pasca%3E35179767%3C/proquest_pasca%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=35179767&rft_id=info:pmid/&rfr_iscdi=true |