Kinetic Resolution of P-Chirogenic Compounds by Palladium-Catalyzed Alcoholysis of Vinyl Ethers

Kinetic Resolution of P-Chirogenic Compounds by Palladium-Catalyzed Alcoholysis of Vinyl Ethers

The palladium‐catalyzed asymmetric alcoholysis of vinyl ethers of P‐chirogenic compounds has been achieved. The kinetic resolution of aryl tert‐butyl(2‐vinyloxyaryl)phosphinates was catalyzed by palladium/chiral diamine complexes with high selectivities (krel: 12–196).

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Veröffentlicht in:Advanced synthesis & catalysis 2009-08, Vol.351 (11-12), p.1796-1800
Hauptverfasser: Itoh, Hisashi, Yamamoto, Eiji, Masaoka, Shigeyuki, Sakai, Ken, Tokunaga, Makoto
Format: Artikel
Sprache:eng
Schlagworte:
alcoholysis
chirality
kinetic resolution
phosphorus
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Beschreibung
Zusammenfassung:The palladium‐catalyzed asymmetric alcoholysis of vinyl ethers of P‐chirogenic compounds has been achieved. The kinetic resolution of aryl tert‐butyl(2‐vinyloxyaryl)phosphinates was catalyzed by palladium/chiral diamine complexes with high selectivities (krel: 12–196).
ISSN:1615-4150
1615-4169
DOI:10.1002/adsc.200900304