A new approach to description of the pressure dependence of viscosity

Based on more precise description of the temperature-pressure dependence of entropy, we expand the Avramov’s model. In this way, viscosity or relaxation time are described with better accuracy. It is demonstrated that there is a strong relation between the fragility parameter F, described here, and...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Journal of non-crystalline solids 2009-05, Vol.355 (10), p.733-736
Hauptverfasser: Avramov, I., Grzybowski, A., Paluch, M.
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Based on more precise description of the temperature-pressure dependence of entropy, we expand the Avramov’s model. In this way, viscosity or relaxation time are described with better accuracy. It is demonstrated that there is a strong relation between the fragility parameter F, described here, and the fragility parameter m, introduced by Angell, m ≈ ( 13 ± 10 % ) F . Analyses of experimental data on dielectric relaxation of phenylphthalein-dimethylether (PDE) are in agreement with the proposed model.
ISSN:0022-3093
1873-4812
DOI:10.1016/j.jnoncrysol.2009.01.031