A new approach to description of the pressure dependence of viscosity
Based on more precise description of the temperature-pressure dependence of entropy, we expand the Avramov’s model. In this way, viscosity or relaxation time are described with better accuracy. It is demonstrated that there is a strong relation between the fragility parameter F, described here, and...
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Veröffentlicht in: | Journal of non-crystalline solids 2009-05, Vol.355 (10), p.733-736 |
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Hauptverfasser: | , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
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Zusammenfassung: | Based on more precise description of the temperature-pressure dependence of entropy, we expand the Avramov’s model. In this way, viscosity or relaxation time are described with better accuracy. It is demonstrated that there is a strong relation between the fragility parameter
F, described here, and the fragility parameter
m, introduced by Angell,
m
≈
(
13
±
10
%
)
F
. Analyses of experimental data on dielectric relaxation of phenylphthalein-dimethylether (PDE) are in agreement with the proposed model. |
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ISSN: | 0022-3093 1873-4812 |
DOI: | 10.1016/j.jnoncrysol.2009.01.031 |