FT-IR, ESI and EPR studies of a Dy(III) Schiff base podand complex

FT-IR, ESI and EPR studies of a Dy(III) Schiff base podand complex

IR spectroscopic, electrospray ionization mass spectrometry, structure and magnetic properties of a dysprosium(III) macroacyclic tripodal Schiff base tris((2-(5-chlorosalicylideno)amino)ethyl)amine ( tren-5Clsal) complex are reported. The positions of ν(C N) stretching bonds indicate that the azomet...

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Veröffentlicht in:Journal of non-crystalline solids 2009-08, Vol.355 (24), p.1355-1359
Hauptverfasser: Leniec, G., Kaczmarek, S.M., Typek, J., Kołodziej, B., Przybylski, P., Brzeziński, B., Grech, E.
Format: Artikel
Sprache:eng
Schlagworte:
Condensed matter: electronic structure, electrical, magnetic, and optical properties
Electron paramagnetic resonance and relaxation
Exact sciences and technology
Magnetic anisotropy
Magnetic properties
Magnetic properties and materials
Magnetic resonances and relaxations in condensed matter, mössbauer effect
Magnetically ordered materials: other intrinsic properties
Physics
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Zusammenfassung:IR spectroscopic, electrospray ionization mass spectrometry, structure and magnetic properties of a dysprosium(III) macroacyclic tripodal Schiff base tris((2-(5-chlorosalicylideno)amino)ethyl)amine ( tren-5Clsal) complex are reported. The positions of ν(C N) stretching bonds indicate that the azomethine group nitrogen is coordinated to the rare earth ion. Two main spectral components are observed in the low magnetic field region (
ISSN:0022-3093
1873-4812
DOI:10.1016/j.jnoncrysol.2009.05.036