Transmission Electron Microscopy Study of CuIn3Se5

The off‐stoichiometric In‐rich phase CuIn3Se5 was studied by means of electron diffraction and high resolution electron microscopy. The structural investigations provide unambigouesly a tetragonal structure of this compound which can be derived from the chalcopyrite structure of CuInSe2. A theoretic...

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Veröffentlicht in:Crystal research and technology (1979) 2000-07, Vol.35 (6-7), p.823-830
Hauptverfasser: Tham, A.-T., Su, D.S., Neumann, W., Schubert-Bischoff, P., Beilharz, C., Benz, K.W.
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Sprache:eng
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Zusammenfassung:The off‐stoichiometric In‐rich phase CuIn3Se5 was studied by means of electron diffraction and high resolution electron microscopy. The structural investigations provide unambigouesly a tetragonal structure of this compound which can be derived from the chalcopyrite structure of CuInSe2. A theoretical model with an ordered occupation of vacancies is discussed for this structure. A detailed comparison between the theoretical model and the experimental archieved one's is revealed.
ISSN:0232-1300
1521-4079
DOI:10.1002/1521-4079(200007)35:6/7<823::AID-CRAT823>3.0.CO;2-R