Combustion Synthesis of NiO/YSZ Composite
Nickel oxide-yttria stabilized zirconia (NiO-YSZ) anode materials were synthesized by combustion process involving metal nitrate-urea decomposition. The precursor was heated to evaporate water undergoing dehydration, and then the mixtures froth and swell. Further heating produces large amounts of ga...
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Veröffentlicht in: | Materials science forum 2008-01, Vol.591-593, p.777-783 |
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Hauptverfasser: | , , , , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | Nickel oxide-yttria stabilized zirconia (NiO-YSZ) anode materials were synthesized by
combustion process involving metal nitrate-urea decomposition. The precursor was heated to
evaporate water undergoing dehydration, and then the mixtures froth and swell. Further heating
produces large amounts of gases that ignite at ambient atmosphere. Different nitrate/urea initial
molar ratios were employed in order to investigate the influence of the reaction temperature in the
physical characteristics of the powder composite. The flame temperature was measured by infrared
optical pyrometer. The combustion was rapid and self-sustaining, with flame temperatures ranging
from 870 to 1330°C. The as-synthesized powders were uniaxially pressed and sintered in air.
Powders were characterized by X-ray diffraction (XRD) analysis, scanning electron microscopy
(SEM), helium picnometry for density measurements and gas adsorption technique (BET). The
ceramic samples were evaluated by SEM and Archimedes density measurements. |
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ISSN: | 0255-5476 1662-9752 1662-9752 |
DOI: | 10.4028/www.scientific.net/MSF.591-593.777 |