Magnetic anisotropy of Ho–Fe–Co–Cr intermetallic compounds

Starting with a Ho 3(Fe 1− x Co x ) 29− y Cr y , ( x, y) = (0.6,4.5) and (0.8,5.5) nominal stoichiometry, a disordered variant of the hexagonal 2:17 phase (Th 2Ni 17-type, S.G. P6 3/ mmc) occurs, since both the monoclinic 3:29 and the transition-metal-rich disordered Th 2Ni 17-type hexagonal compoun...

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Veröffentlicht in:Journal of alloys and compounds 2009-08, Vol.482 (1), p.19-22
Hauptverfasser: Sheloudko, N., Sarafidis, C., Gjoka, M., Efthimiadis, K.G., Kalogirou, O.
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Sprache:eng
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Zusammenfassung:Starting with a Ho 3(Fe 1− x Co x ) 29− y Cr y , ( x, y) = (0.6,4.5) and (0.8,5.5) nominal stoichiometry, a disordered variant of the hexagonal 2:17 phase (Th 2Ni 17-type, S.G. P6 3/ mmc) occurs, since both the monoclinic 3:29 and the transition-metal-rich disordered Th 2Ni 17-type hexagonal compounds have the same rare earth to transition metal ratio, 1:9.7. The magnetic properties and the magnetocrystalline anisotropy of these compounds have been investigated. The anisotropy constant, K's, and the anisotropy field, μ 0 H A, values have been deduced from the magnetization curves measured on powder samples magnetically aligned in a rotating magnetic field. The compound with ( x, y) = (0.8,5.5) shows a compensation point at about 55 K. The magnetic anisotropy of both compounds is that of easy-plane from room temperature to low temperatures down to 5 K.
ISSN:0925-8388
1873-4669
DOI:10.1016/j.jallcom.2009.04.020