Fabrication and characterization of Li0.5Fe2.5O4 octahedrons via a TEA-assisted route

Octahedral-like Li 0.5 Fe 2.5 O 4 crystallites have been fabricated using a TEA-assisted route under mild conditions. The as-prepared powders were characterized in detail by conventional techniques such as XRD, TEM, and FESEM. The saturation magnetization ( M s), remnant magnetization ( M r), and co...

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Veröffentlicht in:Journal of materials science 2008-09, Vol.43 (17), p.5948-5951
Hauptverfasser: Zhang, DongEn, Shu, WenBing, Li, ShanZhong, Zhang, XiaoBo, Ying, Ailing, Tong, ZhiWei
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Sprache:eng
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Zusammenfassung:Octahedral-like Li 0.5 Fe 2.5 O 4 crystallites have been fabricated using a TEA-assisted route under mild conditions. The as-prepared powders were characterized in detail by conventional techniques such as XRD, TEM, and FESEM. The saturation magnetization ( M s), remnant magnetization ( M r), and coercivity ( H c) have been determined to be 84, 6 emu/g, and 85 Oe, respectively. Meanwhile, the electrochemical properties of Li 0.5 Fe 2.5 O 4 demonstrate that it delivers a large discharge capacity, which might find possible application as an electrode material in lithium cells.
ISSN:0022-2461
1573-4803
DOI:10.1007/s10853-008-2856-y